研究目的
Investigating the optimal Yb doping concentration and excitation wavelength for maximizing the ideal laser cooling efficiency in Yb-doped yttrium aluminum garnet (Y:Yb)AG powder crystals using anti-Stokes luminescence.
研究成果
The optimal Yb doping concentration for maximizing the ideal laser cooling efficiency in (Y:Yb)AG powder crystals was found to be 6 mol%. The optimal excitation wavelength was identified as 1030 nm, corresponding to the E3→E5 transition of Yb3+. The ideal cooling efficiency under these conditions was estimated to be 1.9% at room temperature.
研究不足
The study is limited to low Yb doping concentrations to avoid complications from energy transfer processes and cooperative emission. The practical cooling efficiency may be affected by factors not considered in the ideal cooling efficiency model, such as background absorption and non-radiative transitions.
1:Experimental Design and Method Selection:
The study focused on optimizing the Yb doping concentration and excitation wavelength for laser cooling in (Y:Yb)AG powder crystals fabricated by a solid-state reaction method.
2:Sample Selection and Data Sources:
Yb-doped YAG powder crystals with Yb concentrations ranging from 2 to 13 mol% were prepared.
3:List of Experimental Equipment and Materials:
High-purity Y2O3, Al2O3, and Yb2O3 powders were used as starting materials. A semiconductor laser with an oscillation wavelength of 659 nm and a white pulse laser were used for PL measurements.
4:Experimental Procedures and Operational Workflow:
The powders were mixed, sintered at 1700°C, and then crushed into powder. PL measurements were conducted at room temperature.
5:Data Analysis Methods:
The relative cooling efficiency was calculated based on the PL intensity and the ideal cooling efficiency.
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