研究目的
To investigate the use of 1,5-naphthyridine-based conjugated polymers as co-sensitizers in dye-sensitized solar cells (DSSCs) for enhanced photovoltaic performance.
研究成果
The use of 1,5-naphthyridine-based conjugated polymers as co-sensitizers in DSSCs enhances photovoltaic performance, with P2 showing better efficiency and higher charge recombination resistances compared to P1. This approach offers promise for further development of high-efficiency DSSCs.
研究不足
The study focuses on the use of specific conjugated polymers as co-sensitizers and their interaction with N3 dye, which may not be directly applicable to other dye systems. The efficiency improvements, while significant, are modest and may require further optimization for commercial viability.
1:Experimental Design and Method Selection:
Synthesis of 1,5-naphthyridine-based conjugated polymers (P1 and P2) via Horner-Emmons polymerization reaction. Characterization by 1H NMR, TGA, and FT-IR.
2:Sample Selection and Data Sources:
Polymers P1 and P2 were used as co-sensitizers with Ru (II) based N3 dye in DSSCs.
3:List of Experimental Equipment and Materials:
Fluorine doped tin oxide (FTO) conductive glasses, TiO2 paste, N3 dye, P1 and P2 polymers, platinum paste, and electrolyte.
4:Experimental Procedures and Operational Workflow:
Fabrication of DSSCs with TiO2 coated anode sensitized with N3 dye and co-sensitized with P1 or P
5:Measurement of current–voltage (J-V) characteristics and electrochemical impedance spectroscopy (EIS). Data Analysis Methods:
UV–Vis absorption spectra, IPCE spectra, and cyclic voltammetry (CV) for HOMO/LUMO energy levels estimation.
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Source meter
Keithley 2400
Keithley
Measurement of current–voltage (J-V) characteristics
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Fluorine doped tin oxide
FTO TCO22-7/LI
Solaronix
Conductive glass substrate for DSSCs
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Titanium dioxide paste
TiO2 Ti-nanoxide T/SP
Solaronix
Photoanode material for DSSCs
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Ruthenizer
N3 Ruthenizer 535
Solaronix
Photosensitizer for DSSCs
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Electrolyte
Iodolyte AN-50
Solaronix
Electrolyte for DSSCs
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Platinum paste
Pt Platisol T
Solaronix
Counter electrode material for DSSCs
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Solar simulator
IV-5
PV measurements Incorporation
Measurement of current–voltage (J-V) characteristics
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Electrochemical workstation
VMP3 SAS
BioLogic Science Instruments
Cyclic voltammetry (CV) for HOMO/LUMO energy levels estimation
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