研究目的
Investigating the leaching of indium from waste LCD screens by oxalic acid in a temperature-controlled aciduric stirred reactor to improve recovery efficiency and processing ability.
研究成果
The TCASR demonstrated higher efficiency in leaching indium from waste LCD screens with reduced oxalic acid consumption and reaction time. The process was most affected by temperature, and the indium ion concentration maintained stability for 20 min, facilitating subsequent operations. The study suggests the TCASR's potential applicability for indium recovery from waste LCD screens.
研究不足
The study is limited to the leaching of indium from waste LCD screens using oxalic acid in a laboratory-scale reactor. The scalability to industrial levels and the economic feasibility of the process were not extensively explored.
1:Experimental Design and Method Selection
A temperature-controlled aciduric stirred reactor (TCASR) was constructed to investigate the effects of operational conditions on the leaching efficiency of indium. The study focused on optimizing oxalic acid concentration, dosage, temperature, stirring speed, and particle size.
2:Sample Selection and Data Sources
Waste LCD screens were purchased from a waste collection station in Guangzhou, China. ITO glass powder was prepared by manual peeling, washing, drying, and crushing. The content of each element was measured by ICP-OES.
3:List of Experimental Equipment and Materials
Inductively coupled plasma optical emission spectrometer (ICP-OES, 730, Agilent, USA), atomic absorption spectroscopy (AAS, AA6880, Shimadzu, Japan), scanning electron microscope (SEM, SU8220, Hitachi, Japan), X-ray diffractometer (XRD, Empyrean Rheology, Parnco, The Netherlands).
4:Experimental Procedures and Operational Workflow
Leaching experiments were carried out with varying oxalic acid concentrations, dosages, temperatures, stirring speeds, and particle sizes. Leachate was collected at specific intervals, filtered, and analyzed for indium concentration.
5:Data Analysis Methods
Leaching efficiency was calculated, and kinetic models were applied to determine the controlling steps of the leaching process. The effects of various factors on leaching efficiency were analyzed statistically.
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