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[IEEE 2019 Conference on Lasers and Electro-Optics Europe & European Quantum Electronics Conference (CLEO/Europe-EQEC) - Munich, Germany (2019.6.23-2019.6.27)] 2019 Conference on Lasers and Electro-Optics Europe & European Quantum Electronics Conference (CLEO/Europe-EQEC) - Spectral Luminescence Properties of Ho <sup>3+</sup> Ions in Active Media Codoped with Tb <sup>3+</sup> , Pr <sup>3+</sup> and Yb <sup>3+</sup> for Mid-Infrared Laser Development

DOI:10.1109/cleoe-eqec.2019.8872535 出版年份:2019 更新时间:2025-09-11 14:15:04
摘要: Lasers operating in mid-infrared spectral region specifically with 3 m wavelength attract a lot of attention due to their various applications in atmospheric monitoring, medical surgery, remote sensing and scientific research. Such laser can be used as an efficient and high-quality radiation source for optical parametric oscillators and converters to longer IR wavelengths. Laser active media doped with Ho3+ ions are of interest for obtaining the radiation in this spectral range. However the realization of the laser radiation at 5I6 → 5I7 optical transition in Ho3+ ions is a complicated task due to the lack of commercially available laser diodes for efficient pumping of Ho3+ ions. Yb3+ ion is known as an efficient sensitizer for Ho3+ ions in various laser active crystals. The scheme with the excitation transfer from Yb3+ to Ho3+ was realized in Cr:Yb:Ho:YSGG and Cr:Yb:Ho:Eu:YAP lasers with flash lamp pumping [1, 2] and Ho:Yb:GGG and Ho:Yb:YSGG lasers with diode pumping [3]. In addition 5I6 → 5I7 optical transition is known as a “self-terminating” one because the fluorescence lifetime of the lower laser level 5I7 is considerably larger than that of the upper laser level 5I6. Codoping of Ho3+ active media with Tb3+ or Pr3+ ions can accelerate the deactivation process of the lower laser level. The concentration set of CaF2 crystal doped with Ho3+, Yb3+, Tb3+, Pr3+ ions was grown using the Bridgman technique. The number of Gd2O3, Y2O3 single crystal fibers doped with the same ions was successfully obtained by laser-heated pedestal growth method. Absorption spectra of Yb:Ho:Gd2O3 and Yb:Ho:Pr:Gd2O3 crystals showed that Yb3+ doping increased the absorption coefficient within 850-1050nm spectral region and make Yb doped media suitable for efficient pumping by commercially available laser diodes. The fluorescence lifetime of 5I6 and 5I7 manifolds of Ho3+ ions was investigated in CaF2 crystals codoped with Tb3+ and Pr3+ ions. It was found that this codoping resulted in the depopulation of the lower laser level 5I7 in Ho3+ ions and at the same time had little influence on the upper laser level 5I6 (Table 1). The lifetime of the lower laser level reduced from 17.5 ms for Yb:Ho:CaF2 crystal to 0.75 ms for Yb:Ho:Tb:CaF2. Deactivation effect of lower laser level 5I7 in Ho3+ was also observed in Yb3+:Ho3+:Pr3+:Gd2O3 and Yb3+:Ho3+:Tb3+:Gd2O3 single crystal fibers. The lifetime of the lower laser level 5I7 decreased from 8.25 ms to 1.04 ms and to 0.67 ms with a codoping of 0.5 at.% Pr3+ and 0.5 at.% Tb3+ ions, respectively. The use of Yb3+, Tb3+ or Pr3+ codoping with Ho3+ to enhance the laser properties of Ho3+ ions at 5I6→5I7 optical transition at the wavelength of ~2.8-3 μm were investigated in the Gd2O3, Y2O3 single crystal fiber for the first time. Obtained results indicate that single crystal fiber Yb3+:Ho3+:Tb3+:Gd2O3 and CaF2 :Yb3+:Ho3+:Tb3+ crystal is a promising laser medium for developing compact LD-pumped lasers operating at the wavelength of 2.8-3 μm.
作者: Petr G. Zverev,Vasily A. Konyushkin,Anatoly A. Sirotkin,Sergey Ya. Rusanov
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Investigating the spectral luminescence properties of Ho3+ ions in active media codoped with Tb3+, Pr3+ and Yb3+ for mid-infrared laser development.

The study demonstrates that codoping Ho3+ active media with Yb3+, Tb3+, or Pr3+ ions can significantly reduce the fluorescence lifetime of the lower laser level 5I7, making these materials promising for developing compact LD-pumped lasers operating at the wavelength of 2.8-3 μm.

The study is limited by the specific dopants and host materials used, and the findings may not be directly applicable to other systems without further investigation.

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