研究目的
Developing a high sensitivity optical thermometer using exciton recombination of CsPbBr3 quantum dots and 4f→4f transition of Eu3t ions as temperature detecting and reference signals, respectively.
研究成果
The Eu3t-doped CsPbBr3 PQDs@glass nanocomposite exhibits excellent temperature sensing performance with high sensitivity, making it a promising material for optical thermometry applications.
研究不足
The study focuses on the temperature range from 93 K to 383 K. The sensitivity and accuracy of the optical thermometer may vary outside this range.
1:Experimental Design and Method Selection:
The study involved the fabrication of Eu3t-doped tellurite glasses embedding CsPbBr3 PQDs through a melt-quenching method followed by controlled in-situ glass crystallization.
2:Sample Selection and Data Sources:
Samples with varying contents of perovskite-related components and EuF3 were prepared.
3:List of Experimental Equipment and Materials:
X-ray diffraction (XRD) analysis, transmission electron microscope (TEM), Fourier transform infrared spectra (FTIR), Raman spectra, Photoluminescence (PL), PL excitation (PLE) spectra, and decay curves were recorded.
4:Experimental Procedures and Operational Workflow:
The mixed raw materials were melted, poured into a mold to achieve precursor glass, and then heat-treated to form CsPbBr3 PQDs@glass.
5:Data Analysis Methods:
The temperature-dependent PL spectra were analyzed to explore the application in optical thermometry.
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MiniFlex600 Rigaku
MiniFlex600
Rigaku
X-ray diffraction analysis
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JEM-2010
JEM-2010
JEOL
Transmission electron microscope
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LabRam HR Raman spectrometer
LabRam HR
Horiba Jobin Yvon
Raman spectra determination
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Fluorolog 3–22 spectrofluorometer
Fluorolog 3–22
Horiba Jobin Yvon
Photoluminescence (PL), PL excitation (PLE) spectra, and decay curves measurement
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THMS 600
THMS 600
Linkam
Temperature measurements
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