研究目的
Investigating the impact of back contact selenization (preeSe) and external biases (light/voltage) on the heat degradation of Cu(In,Ga)Se2 (CIGS) solar cells and modules.
研究成果
The study concludes that back electrode pre-selenization significantly affects the heat stability of CIGS solar cells, with reduced pre-selenization leading to improved initial efficiency but stronger heat degradation. Application of external bias during heat exposure can mitigate degradation effects, suggesting that both interfacial and bulk properties of the absorber film are influenced by processing conditions and biases.
研究不足
The study is limited to specific pre-selenization conditions and biases, and the exact origin and location of the in-stack energy barrier affecting FF changes are not fully understood.
1:Experimental Design and Method Selection:
The study involves accelerated heat degradation tests on fully encapsulated CIGS modules under different pre-selenization conditions and biases.
2:Sample Selection and Data Sources:
Measurements are done on flexible (Ag,Cu)(In,Ga)Se2 solar cells fabricated at the MiaSolé manufacturing line.
3:List of Experimental Equipment and Materials:
Includes a roll coater for deposition, a Sula deep-level-transient spectrometer for capacitance-voltage profiling, and a Janis cryostat for temperature-dependent current-voltage measurements.
4:Experimental Procedures and Operational Workflow:
Light-soaking and heat exposure tests are conducted under controlled conditions, followed by J-V and EQE measurements.
5:Data Analysis Methods:
Data is analyzed to extract carrier concentration, depletion widths, and to understand the mechanisms of degradation.
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