研究目的
Investigating the effects of zone melting recrystallization on microcrystalline silicon ribbons obtained by chemical vapor deposition for potential applications in solar cells.
研究成果
The physical characteristics of the μc-Si ribbon, such as powder substrate incorporation, porosity, and thickness, significantly influence the recrystallization process and the electrical properties of the resulting mc-Si ribbon. Improvements in reducing impurity content and porosity are necessary to enhance the quality of the recrystallized ribbons for solar cell applications.
研究不足
The presence of a thin oxide layer over the molten zone during some ZMR runs causes superficial recrystallization and possibly a high concentration of oxygen in the mc-Si ribbon. The high porosity of the μc-Si ribbon favors the incorporation of oxygen, and powder substrate incorporation during the CVD step is significant, affecting the quality of the recrystallized ribbon.
1:Experimental Design and Method Selection:
The study uses an optical zone melting recrystallization (ZMR) system to recrystallize microcrystalline silicon (μc-Si) ribbons obtained from a chemical vapor deposition (CVD) system. The ZMR system focuses radiation from two halogen lamps to create a molten zone on the silicon ribbon.
2:Sample Selection and Data Sources:
μc-Si ribbon samples measuring up to 25×100 mm2 were used, grown on silicon dust substrates in the CVD system.
3:List of Experimental Equipment and Materials:
The ZMR system includes two 1000 W tubular halogen lamps, elliptical mirrors, a step motor for ribbon movement, and operates in an argon atmosphere.
4:Experimental Procedures and Operational Workflow:
The μc-Si ribbon is recrystallized by moving it through the molten zone at a constant speed between 1 to 6 mm/min. The process is monitored for stability and quality of recrystallization.
5:Data Analysis Methods:
Characterization of the recrystallized mc-Si ribbons includes four-point probe resistivity measurements and contactless microwave photoconductance decay (μ-PCD) lifetime measurements.
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