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AIP Conference Proceedings [AIP Publishing 15th International Conference on Concentrator Photovoltaic Systems (CPV-15) - Fes, Morocco (25–27 March 2019)] 15th International Conference on Concentrator Photovoltaic Systems (CPV-15) - Zone melting recrystallization of microcrystalline silicon ribbons obtained by chemical vapor deposition

DOI:10.1063/1.5123895 出版年份:2019 更新时间:2025-09-12 10:27:22
摘要: We present the results achieved with an optical zone melting recrystallization (ZMR) system, which concentrates the radiation of two halogen lamps on the surface of a microcrystalline silicon (μc-Si) ribbon sample, creating a long, 2 mm width molten region (~1414o C). μc-Si ribbon samples measuring up to 25×100 mm2 were previously obtained using an inline optical chemical vapor deposition (CVD) system, that grows silicon layers on top of a silicon dust substrate. Inside the ZMR system, the μc-Si ribbon sample is recrystallized in an argon atmosphere and using a step motor to pull the ribbon at a constant speed between 1 to 6 mm/min, the molten zone travels along the ribbon, recrystallizing the whole sample into a multi-crystalline silicon (mc-Si) ribbon, with an average crystal size in the [1; 10] mm range. It was observed that the physical characteristics of the μc-Si ribbon, like powder substrate incorporation, porosity, thickness, powder grain size used as substrate in the CVD step, have a crucial influence on the recrystallization process and on the electrical properties of the mc-Si ribbon obtained after the ZMR process. Lifetime measurements performed on the recrystallized samples suggest that improvements regarding crystalline quality and possible presence of impurities need to be addressed.
作者: Filipe C. Serra,Elmahdi Amar,David R. Pêra,José A. Silva,Jo?o M. Serra
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Investigating the effects of zone melting recrystallization on microcrystalline silicon ribbons obtained by chemical vapor deposition for potential applications in solar cells.

The physical characteristics of the μc-Si ribbon, such as powder substrate incorporation, porosity, and thickness, significantly influence the recrystallization process and the electrical properties of the resulting mc-Si ribbon. Improvements in reducing impurity content and porosity are necessary to enhance the quality of the recrystallized ribbons for solar cell applications.

The presence of a thin oxide layer over the molten zone during some ZMR runs causes superficial recrystallization and possibly a high concentration of oxygen in the mc-Si ribbon. The high porosity of the μc-Si ribbon favors the incorporation of oxygen, and powder substrate incorporation during the CVD step is significant, affecting the quality of the recrystallized ribbon.

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