研究目的
Investigating the enhancement of luminescence and stability of CsPbBr3 perovskite quantum dots in borosilicate glass through the incorporation of silver nanoparticles.
研究成果
Ag NP doped CsPbBr3 QD glass exhibits enhanced photoluminescence due to localized surface plasmon resonance coupling, with the 0.1 molar ratio Ag2O doped sample showing the highest enhancement. The glass samples demonstrate excellent thermal and water stability, making them promising for optoelectronic applications.
研究不足
The study is limited by the spectral self-absorption effect of Ag NPs at high doping concentrations, which reduces photoluminescence intensity. Additionally, the stability of QDs on the glass surface against hydrolysis is a concern.
1:Experimental Design and Method Selection:
The glass was prepared using a conventional melt quenching method, with the molar ratio of the sample being 35B2O3-40SiO2-10ZnO-6Cs2CO3-4PbBr2-5NaBr-xAg2O (x = 0, 0.1, 0.2, 0.4). The uniformly mixed sample was melted at 1200 ℃ for 15 minutes in an air atmosphere, then annealed at 350 ℃ for 10 hours, and heat treated for 5 hours at 475 ℃ to obtain CsPbBr3 QDs glass.
2:1, 2, 4). The uniformly mixed sample was melted at 1200 ℃ for 15 minutes in an air atmosphere, then annealed at 350 ℃ for 10 hours, and heat treated for 5 hours at 475 ℃ to obtain CsPbBr3 QDs glass.
Sample Selection and Data Sources:
2. Sample Selection and Data Sources: The samples obtained were named G0, G0.1, G0.2 and G0.4 based on the Ag2O doping concentration.
3:1, G2 and G4 based on the Ag2O doping concentration.
List of Experimental Equipment and Materials:
3. List of Experimental Equipment and Materials: Alumina crucible, muffle furnace, copper plate, and optical polishing equipment were used.
4:Experimental Procedures and Operational Workflow:
The molten glass liquid was poured onto a preheated copper plate to obtain a precursor glass, which was then annealed and heat treated to form CsPbBr3 QDs glass.
5:Data Analysis Methods:
XRD, TEM, PL spectra, and PL decay curves were used to characterize the samples.
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