研究目的
To study the degradation of perovskite solar cells (PSCs) under multiple environmental conditions using a multivariate approach to identify the most and least significant factors affecting stability.
研究成果
The multivariate approach successfully identified the most and least significant factors affecting PSC stability, with oxygen exposure being the most significant. The most stable device configuration was NiOx/MAPbBr2I/PC70BM/LiF/Ag, demonstrating the effectiveness of the PB screening technique in optimizing PSC stability.
研究不足
The study is limited by the choice of two levels for each factor in the PB screening technique, which may not capture the full range of possible variations. Additionally, the study focuses on a specific set of materials and device configurations, which may not be universally applicable.
1:Experimental Design and Method Selection:
A Plackett Burman (PB) screening design was used to analyze 9 different factors affecting PSC stability, including four extrinsic (oxygen, moisture, UV exposure, temperature) and five intrinsic factors (hole transport layer, electron transport layer, absorber layer thickness, halide type, perovskite deposition process).
2:Sample Selection and Data Sources:
Samples were fabricated on glass substrates with variations in HTL, perovskite composition, thickness, and deposition process.
3:List of Experimental Equipment and Materials:
Included PEDOT:PSS, NiOx, MAPbI3, MAPbBr2I, PC70BM, LiF, and Ag for electrode.
4:Experimental Procedures and Operational Workflow:
Samples were exposed to controlled environmental conditions in a UHV chamber, with absorption measurements and device characterization performed under specific stress factors.
5:Data Analysis Methods:
Multivariate analysis was conducted using a software package (Reliasoft) to determine the significance of each factor on stability.
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