研究目的
Exploring novel low-cost electrode materials with higher energy and power densities for supercapacitors.
研究成果
The CdS-MAPI3 electrodes exhibit highest areal capacitance of 141 μFcm-2 and highest energy density of 23.8 nWhcm-2 with retention of more than 87 % up to 4000 cycles, highlighting a very good cyclic stability. The work demonstrates the potential of using CdS quantum dots and organohalides perovskite-based bilayer electrodes for high-performance supercapacitors.
研究不足
The study focuses on the fabrication and initial testing of the supercapacitors, but long-term stability and scalability for commercial applications are not extensively discussed.
1:Experimental Design and Method Selection:
Fabrication of thin film electrochemical capacitors using layers of self-synthesized cadmium sulfide quantum dots and organometallic halide perovskite materials as active electrodes.
2:Sample Selection and Data Sources:
Self-synthesized CdS quantum dots using pulsed laser ablation in liquid technique and one-step solution processed perovskites.
3:List of Experimental Equipment and Materials:
Cadmium sulfide (CdS,
4:9%, Sigma Aldrich), Bismuth(III) iodide (BiI3, 9%, Sigma-Aldrich), Lead (II) iodide (PbI2, 9%, Sigma Aldrich), Methyl ammonium iodide (CH3NH3I, 99 %, Sigma Aldrich), anhydrous N,N-dimethylformamide (DMF, 8%, Sigma-Aldrich), Poly vinyl alcohol (PVA, Fluker AG), 2-propanol (5 %, Sigma Aldrich), Chlorobenzene (anhydrous 8 %), Potassium hydroxide (KOH) pellets (85 %, Sigma Aldrich), fluorine-doped tin oxide (FTO) glass (15 ?sq-1, Solaronix), acetone (5 %, Gainland Chemical Company), ethanol (8 %, Sigma Aldrich). Experimental Procedures and Operational Workflow:
Fabrication of electrodes through facile and inexpensive solution process coating.
5:Data Analysis Methods:
Cyclic voltammetry (CV) profiles and electrochemical impedance spectroscopy (EIS) measurement were conducted, using AUTOLAB PG302N equipped with NOVA 2.1 software.
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Bismuth(III) iodide
BiI3
Sigma-Aldrich
Perovskite precursor
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N,N-dimethylformamide
DMF
Sigma-Aldrich
Solvent
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Cadmium sulfide
CdS
Sigma Aldrich
Active electrode material
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Lead (II) iodide
PbI2
Sigma Aldrich
Perovskite precursor
-
Methyl ammonium iodide
CH3NH3I
Sigma Aldrich
Perovskite precursor
-
Poly vinyl alcohol
PVA
Fluker AG
Electrolyte component
-
2-propanol
Sigma Aldrich
Solvent
-
Chlorobenzene
Solvent
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Potassium hydroxide
KOH
Sigma Aldrich
Electrolyte component
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Fluorine-doped tin oxide glass
FTO
Solaronix
Substrate
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Acetone
Gainland Chemical Company
Solvent
-
Ethanol
Sigma Aldrich
Solvent
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AUTOLAB PG302N
PG302N
Electrochemical measurements
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NOVA 2.1 software
2.1
Data analysis
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Field emission scanning electron microscope
Lyra TESCAN
Morphology characterization
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