研究目的
Investigating the influence of fluorescence lifetime on the scattering and nanofiber distribution of nanofibers with various shapes of silver nanoparticles (Ag NPs) embedded within for random lasers and white-light-emitting diodes.
研究成果
The study demonstrated emission enhancement and lower threshold in nanofibers with Ag NPs due to improved LSPR and scattering effects. The fabricated white LEDs with nanofibers showed potential for backlight displays and other photonic applications.
研究不足
The study focuses on the influence of Ag NPs' shape and size on RLs and LEDs, but the scalability and long-term stability of the fabricated devices under various environmental conditions were not extensively explored.
1:Experimental Design and Method Selection:
Prepared polyvinyl alcohol (PVA) nanofibers with Ag NPs through electrospinning (ES) and pyrromethene 597 dye doping.
2:Sample Selection and Data Sources:
Used Ag NPs of distinct shapes and sizes, characterized through UV–Vis and TEM analysis.
3:List of Experimental Equipment and Materials:
Included a 532-nm Q-switch nanosecond laser, SEM, TEM, UV–Vis spectrophotometer, and spectrofluorometer.
4:Experimental Procedures and Operational Workflow:
Fabricated nanofibers through ES, drop-coated PM597 dye, and annealed. Characterized the samples' optical properties and performed backscattering measurements.
5:Data Analysis Methods:
Analyzed emission spectra, mean free path, and PL lifetime using biexponential fitting.
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Q-switch nanosecond laser
NL200 series
EKSPLA
Optical excitation of samples for RL emission spectra characterization
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SEM
Hitachi S-520
Hitachi
Characterization of electrospun nanofibers' morphologies
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TEM
Characterization of Ag NPs' shapes and sizes
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UV–Vis spectrophotometer
Shimadzu
Recording UV–Vis absorption spectra
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spectrofluorometer
Fluorolog-3
Horiba Jobin Yvon
Recording PL spectra and LSPR of Ag NPs
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