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Microfluidic Channels Fabrication Based on Underwater Superpolymphobic Microgrooves Produced by Femtosecond Laser Direct Writing

DOI:10.1021/acsapm.9b00269 期刊:ACS Applied Polymer Materials 出版年份:2019 更新时间:2025-09-12 10:27:22
摘要: A strategy is proposed here to fabricate microfluidic channels based on underwater superpolymphobic microgrooves with nanoscale rough surface structure on glass surface produced by femtosecond (fs) laser processing. The fs laser-induced micro/nanostructure on glass surface is able to repel liquid polydimethylsiloxane (PDMS) underwater, with the contact angle (CA) of 155.5 ± 2.5° and CA hysteresis of 2.7 ± 1.5° to a liquid PDMS droplet. Such phenomenon is defined as the underwater “superpolymphobicity”. Microchannels as well as microfluidic systems are easily prepared and formed between the underwater superpolymphobic microgrooves-textured glass substrate and the cured PDMS layer. Because the tracks of the laser scanning lines are programmable, arbitrary-shaped microchannels and complex microfluidic systems can be potentially designed and prepared through fs laser direct writing technology. The concept of “underwater superpolymphobicity” presented here offers us a new strategy for selectively avoiding the adhesion at the polymer/substrate interface and controlling the shape of cured polymers, none of these applications can find analogs in previously reported superwetting materials.
作者: Jiale Yong,Zhibing Zhan,Subhash Chandra Singh,Feng Chen,Chunlei Guo
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To propose a simple strategy for fabricating microfluidic channels based on underwater superpolymphobic microgrooves with nanoscale rough surface structure on glass surface produced by femtosecond laser processing.

The study demonstrates a simple strategy to fabricate microfluidic channels based on the underwater superpolymphobicity of fs laser-structured microgrooves. The laser-induced micro/nanostructures have the ability to repel liquid PDMS underwater, enabling the preparation of microchannels between glass substrates and PDMS layers. The programmable nature of laser scanning allows for the design of arbitrary-shaped microchannels and complex microfluidic systems. The concept of underwater superpolymphobicity offers new strategies for controlling polymer adhesion and shape, with potential applications in polymer preparation, casting industry, and 3D printing technology.

The study is limited to the fabrication of microfluidic channels on glass substrates using femtosecond laser processing. The size of the microchannels is determined by the laser power and scanning interval, which may limit the resolution and complexity of the microfluidic systems that can be fabricated.

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