研究目的
Investigating the highly efficient and ultrafast adsorption of methylene blue (MB) by K2Ti8O17 nanowires for wastewater treatment.
研究成果
K2Ti8O17 nanowires exhibit high and ultrafast adsorption capacity for MB, attributed to their large surface area, mesoporous structure, and unique tunnel-layered structure. The adsorption process is spontaneous, exothermic, and follows the pseudo-second-order kinetic model and Langmuir isotherm. The nanowires also show potential for the removal of chromium (VI) ions and photocatalytic degradation of NO, making them promising materials for water purification and air treatment.
研究不足
The study focuses on the adsorption of MB and does not extensively explore the adsorption mechanisms of other pollutants. The photocatalytic properties of K2Ti8O17 nanowires are mentioned but not deeply investigated.
1:Experimental Design and Method Selection:
K2Ti8O17 nanowires were synthesized by a one-step hydrothermal method using TiO2 and KOH as raw materials. The synthesis conditions such as temperature, KOH concentration, and reaction time were varied to control the morphology and phase purity of the nanowires.
2:Sample Selection and Data Sources:
Anatase titanium dioxide (98.8%) and potassium hydroxide (85%) were used without further purification. The samples were characterized by XRD, FESEM, HRTEM, XPS, UV-vis-NIR spectrophotometer, Raman spectrometer, FTIR, and BET surface area analysis.
3:8%) and potassium hydroxide (85%) were used without further purification. The samples were characterized by XRD, FESEM, HRTEM, XPS, UV-vis-NIR spectrophotometer, Raman spectrometer, FTIR, and BET surface area analysis. List of Experimental Equipment and Materials:
3. List of Experimental Equipment and Materials: Stainless steel autoclave, X-ray diffractometer (XRD, D/Max2550, Rigaku, Japan), field emission scanning electron microscopy (FESEM, Hitachi, S-4800), high-resolution transmission electron microscopy (HRTEM, Tecnai G2F20 S-TWIN, FEI, USA), X-ray photoelectron spectrometer (ESCALAB MKII, VG40 Scientific, UK), UV-vis-NIR spectrophotometer (Lambda 950, Perkin-Elmer, USA), Microscopic Confocal Laser Raman spectrometer (Via Reflex, Renishaw, UK), V70 FTIR spectrophotometer (Bruker), Micromeritics ASAP 2020 system for BET analysis.
4:Experimental Procedures and Operational Workflow:
The hydrothermal reaction was carried out at different temperatures and KOH concentrations. The products were washed with distilled water and ethanol, dried, and then characterized. Adsorption experiments were conducted with MB as a model pollutant under various conditions.
5:Data Analysis Methods:
The adsorption data were analyzed using pseudo-first-order, pseudo-second-order kinetic models, Langmuir and Freundlich isotherm models, and thermodynamic parameters were calculated.
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X-ray diffractometer
D/Max2550
Rigaku
Identification of crystal structure
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Field emission scanning electron microscopy
S-4800
Hitachi
Determination of microstructure and morphology
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High-resolution transmission electron microscopy
Tecnai G2F20 S-TWIN
FEI
Investigation of detailed crystalline behaviors
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UV-vis-NIR spectrophotometer
Lambda 950
Perkin-Elmer
Measurement of UV-vis diffuse reflectance spectra
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FTIR spectrophotometer
V70
Bruker
Fourier transform infrared analysis
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X-ray photoelectron spectrometer
ESCALAB MKII
VG40 Scientific
Evaluation of chemical state of elements
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Microscopic Confocal Laser Raman spectrometer
Via Reflex
Renishaw
Measurement of Raman spectra
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Micromeritics ASAP 2020 system
ASAP 2020
Micromeritics
Evaluation of specific surface areas and porosity
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