研究目的
To investigate the fundamental physics of the light-matter interactions in all-inorganic lead halide perovskites, focusing on strong exciton-photon coupling and coherent photonic lasing in a high-quality self-assembled CsPbBr3 perovskite microcuboid.
研究成果
The research demonstrated strong exciton-photon coupling and coherent photonic lasing in CsPbBr3 perovskite microcuboids, with a vacuum Rabi splitting up to 309 meV and a high Q-factor of 4153. The study revealed the transition from strong to weak coupling regimes under the competition between gain and internal loss, offering insights for the development of micro-nano photoelectric devices.
研究不足
The study is limited by the crystallinity and uniformity of the self-assembled lead halide perovskite microcavities, which can affect the interference patterns and lasing properties. Additionally, the optical test system's alignment and collimation may introduce non-uniformity in the collected data.
1:Experimental Design and Method Selection:
The study utilized a chemical vapor deposition (CVD) method to grow high-quality CsPbBr3 perovskite microcuboids. Angle-resolved photoluminescence (ARPL) spectra techniques were employed to observe the energy-wavevector (E-k) dispersion behavior and strong exciton-photon coupling.
2:Sample Selection and Data Sources:
The CsPbBr3 microcuboids were synthesized on SiO2/Si substrates, with specific dimensions and properties selected for study.
3:List of Experimental Equipment and Materials:
A horizontal quartz tube furnace, gas mass flowmeter, vacuum pump, SEM (JSM-7800F Prime Microscope), XRD (Bruker AXS D8 Diffractometer), UV-vis absorption spectra (Cary 5000 UV-VIS-NIR spectrophotometer), and a home-built ARPL system with Fourier optics were used.
4:Experimental Procedures and Operational Workflow:
The microcuboids were excited with a 400nm pulsed laser, and the PL emission was analyzed to study lasing properties and exciton-polaritons.
5:Data Analysis Methods:
The coupled oscillators model (COM) was used to fit polariton mode dispersion, and finite-difference time domain method (FDTD) simulations were conducted to analyze electric field distributions.
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