摘要： In this work, a novel, economical and effective vessel–like biochar–based photocatalyst Bi2S3/BiOBr/BC was synthesized by a facile one–pot solvothermal method for the first time. A series of characterization analyses demonstrated the successful preparation of photocatalyst Bi2S3/BiOBr/BC. Furthermore, diclofenac (DCF) as the target contaminant was applied to elucidate the enhanced photocatalytic performance (93.65%, 40 min) under energy–saving visible LED light irradiation. Comparison experiments among different photocatalysts and photoelectrochemical tests results illustrated that excellent photocatalytic performance of Bi2S3/BiOBr/BC 10% might be attributed to the electrons transfer of biochar and higher charge separation efficiency of heterojunction structure. Besides, lower electrical energy per order value indicated photocatalyst/visible LED light system was more energy–saving. Proper photocatalyst dosage (0.6 g/L) and relatively acidic water environment (pH=5.0) would be beneficial to DCF photodegrdation by Bi2S3/BiOBr/BC. Good reusability and stability of Bi2S3/BiOBr/BC were verified via five consecutive recycle experiments. Furthermore, the role of active species was determined through trapping experiments and ·O2– and h+ dominated the photodegradation reaction to mineralize DCF molecules. Eleven main intermediates and four possible photodegradation pathways were proposed by HRMS analysis. Accordingly, photocatalyst Bi2S3/BiOBr/BC would provide potential technical support for emerging pollutant removal in water matrix.