研究目的
To develop flexible high-efficiency CZTSSe solar cells on diverse flexible substrates via an adhesive-bonding transfer method.
研究成果
The study successfully demonstrated the fabrication of flexible high-efficiency CZTSSe solar cells on diverse substrates using an adhesive-bonding transfer method, achieving PCEs of up to 7.1% on PET substrates. The research provides insights into the potential for making flexible solar cells with this method, despite some limitations in PCE degradation and flexibility.
研究不足
The study faced challenges in maintaining the PCE of the transferred solar cells, with some degradation observed due to damage during the scribing process. The flexibility of the solar cells was also limited to a bending radius greater than 1 cm.
1:Experimental Design and Method Selection:
The study involved the fabrication of CZTSSe solar cells on soda-lime glass (SLG) via a high-temperature annealing process, followed by transferring these cells to flexible substrates using an adhesive-bonding transfer method.
2:Sample Selection and Data Sources:
The samples included CZTSSe solar cells fabricated on SLG and transferred to PET, paper, and cloth substrates.
3:List of Experimental Equipment and Materials:
Equipment included RF magnetron sputtering for Mo layer deposition, DC magnetron sputtering for Zn and Cu layers, and RF magnetron sputtering for Sn layer. Materials included Se and S powders for the annealing process, KCN solution for secondary phase elimination, and conductive epoxy for transfer.
4:Experimental Procedures and Operational Workflow:
The process involved mechanical and chemical etching to remove the rigid glass substrate, protection of the CZTSSe cells with PMMA and TRT, and transfer to flexible substrates using conductive epoxy.
5:Data Analysis Methods:
Characterization techniques included SEM, TEM-EDX, XRD, Raman spectroscopy, EQE measurements, and solar simulator testing under AM 1.5G conditions.
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SEM
Hitachi S-4700
Hitachi
Analysis of CZTSSe absorption layers and TRT
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RF magnetron sputtering
Deposition of Mo, Zn, Cu, and Sn layers
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DC magnetron sputtering
Deposition of Zn and Cu layers
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Thermal release tape
Supporting layer during transfer process
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Poly (methyl methacrylate)
PMMA
Protection layer for CZTSSe solar cells
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Conductive epoxy
CW2400
Circuitworks
Adhesive bonding for transfer to flexible substrates
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Solar simulator
WXS-155S-L2
WACOM
Measurement of solar cell parameters under AM 1.5G conditions
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TEM-EDX
Analysis of CZTSSe absorption layers
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XRD
X'pert-APD
Philips
Analysis of crystallinity of absorption layers
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Raman spectrometer
Renishaw
Raman spectrum analysis of CZTSSe thin film
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EQE measurement system
QEX7
PV Measurements
Quantum efficiency and bandgap analysis
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