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Role of surface recombination in perovskite solar cells at the interface of HTL/CH3NH3PbI3

DOI:10.1016/j.nanoen.2019.104186 期刊:Nano Energy 出版年份:2019 更新时间:2025-09-19 17:13:59
摘要: In order to achieve the highest performance of organometal trihalide perovskite solar cells, it is required to recognize the dominant mechanisms which play a key role in a perovskite material. In the following studies, we have focused on the interfacial recombination between the hole transporting layer (HTL) and the perovskite CH3NH3PbI3 in solar cell devices with p–i–n architecture. It has been shown that Cu∶NiOx used as HTL drastically decreases a short–circuit photocurrent (Jsc) and an open–circuit voltage (Voc). However, we have found that an addition of PTAA thin layer improves cells quality and, as a consequence, the efficiency of such solar cells increases by 2%. Here, we explain both Jsc and Voc losses with a theory of the "dead layer" of perovskite material where a very high surface recombination occurs. We demonstrate the numerical and experimental studies by the means of series detailed analyses to get in–depth understanding of the physical processes behind it. Using a drift–diffusion model, it is shown that the presence of a parasitic recombination layer influences mostly the current distribution in the simulated samples explaining Jsc and Voc losses. The following results could be useful for improving the quality of perovskite solar cells.
作者: Damian G?owienka,Dong Zhang,Francesco Di Giacomo,Mehrdad Najafi,Sjoerd Veenstra,J?drzej Szmytkowski,Yulia Galagan
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To investigate and understand the role of recombination processes which occur at the interface of HTL/perovskite in perovskite solar cells.

The presence of a dead (recombination) layer at the interface of HTL/perovskite in the solar cell with Cu∶NiOx as HTL leads to significant recombination losses, affecting the photocurrent and voltage. Passivation with PTAA material reduces these losses, improving the cell's efficiency. The study provides insights into recombination mechanisms in perovskite solar cells, which could be useful for improving their performance.

The study focuses on the interface between HTL and perovskite in p–i–n architecture solar cells. The findings may not be directly applicable to other architectures or materials without further investigation.

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