研究目的
Investigating the use of natural dyes from morti?o (Vaccinium ?oribundum) as sensitizers in solar cells to provide an environmentally friendly alternative to synthetic sensitizers.
研究成果
Dyes extracted from morti?o fruits were successfully used as sensitizers in DSSC, with efficiencies between 0.18–0.26%. The extraction medium significantly influenced the efficiency, with TFA-acidified methanol yielding the best results. The study confirms the potential of morti?o dyes as an environmentally friendly alternative to synthetic sensitizers, despite their lower efficiency.
研究不足
The study acknowledges the low power conversion efficiency of morti?o dye-sensitized solar cells compared to synthetic sensitizers. Further research is needed to identify which components of the dye extracts contribute most to efficiency and to study factors like dye concentration and co-adsorption effects.
1:Experimental Design and Method Selection:
The study involved the extraction of dyes from morti?o using acidified methanol (HCl, citric acid, and TFA) and their characterization through HPLC, TLC, and spectrometric methods (UV-Vis, IR, and MS-MALDI). The construction and characterization of dye-sensitized solar cells (DSSC) were performed under standard conditions.
2:Sample Selection and Data Sources:
Morti?o (V. floribundum) samples were purchased from popular markets in Quito, washed, dried, and ground. The dyes were extracted and characterized.
3:List of Experimental Equipment and Materials:
Included methanol, TFA, HCl, citric acid, TiO2 paste, FTO substrates, and various analytical instruments like HPLC, UV-Vis spectrophotometer, and MALDI mass spectrometer.
4:Experimental Procedures and Operational Workflow:
Dye extraction, purification, characterization, and application in DSSC construction. The DSSC performance was evaluated under simulated sunlight.
5:Data Analysis Methods:
The efficiency of DSSC was analyzed using ANOVA to determine the effect of different extraction acids on photovoltaic parameters.
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