研究目的
Investigating the synthesis of hierarchical TiO2 nanotubes for highly efficient dye-sensitized solar cells.
研究成果
The anatase HTNTs are composed of omnidirectional nanorod branches on the nanotube steam surfaces, which is an effective structure to balance the light-harvesting, the charge transport and specific surface area. The DSSC based on HTNTs yields a superior g of 9.89%, which is higher than that of P25 (8.34%).
研究不足
The length of hierarchical TiO2 NTAs is still less than 19 lm using PTO, DEG and H2O by a one-step hydrothermal method, and the efficiency of the cell based on such hierarchical TiO2 NTAs is still less than 8%.
1:Experimental Design and Method Selection
One-step hydrothermal method employing potassium titanium oxalate, ethanol and H2O.
2:Sample Selection and Data Sources
FTO glass substrates treated by using the TiO2 collosol to form a seed-layer.
3:List of Experimental Equipment and Materials
Potassium titanium oxalate (PTO), ethanol, N719 dye, FTO glass substrates, field emission scanning electron microscopy (FESEM, JEOL JSM-7100F), transmission electron microscopy (TEM, JEOL JEM-2100PLUS), X-ray diffraction (XRD, Rigaku Ultima IV), Uv–vis spectrometry (UV-2600, SHIMADZU Excellence in Science Co., Ltd., Japan).
4:Experimental Procedures and Operational Workflow
Hydrothermal reaction at 200°C for different times (3, 6, 9, 12 and 15 h). After the reaction, samples were rinsed with deionized water and calcined at 500°C for 1 h.
5:Data Analysis Methods
Characterization by FESEM, TEM, XRD, DRS, IPCE measurement, EIS analysis.
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Field emission scanning electron microscopy
JEOL JSM-7100F
JEOL
Used for morphology characterization of samples.
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Transmission electron microscopy
JEOL JEM-2100PLUS
JEOL
Used for detailed structural analysis of samples.
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X-ray diffraction
Rigaku Ultima IV
Rigaku
Used for phase analysis of samples.
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Potassium titanium oxalate
Shanghai Macklin Biochemical Co., Ltd.
Used in the synthesis of hierarchical TiO2 nanotubes.
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Ethanol
Xilong Scienti?c Co., Ltd.
Used as a solvent in the hydrothermal synthesis.
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N719 dye
Everlight Chemical Industrial Corp., Taiwan
Used as a sensitizer in dye-sensitized solar cells.
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FTO glass
14 X cm?2
Nippon Sheet Glass Co., Ltd.
Used as a transparent conducting oxide substrate.
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Uv–vis spectrometry
UV-2600
SHIMADZU Excellence in Science Co., Ltd., Japan
Used for diffuse reflectance spectra measurements.
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