研究目的
Developing transparent counter electrode materials for bifacial dye-sensitized solar cells to address the needs of window-transparent-type building-integrated photovoltaics.
研究成果
The MoS2/PEDOT composite counter electrodes demonstrate superior conductivity and catalytic properties, making them excellent candidates for bifacial DSSCs in building-integrated photovoltaics. The optimized DSSCs achieve a PCE of 7% under front illumination and 4.82% under back illumination.
研究不足
The study focuses on the optimization of MoS2/PEDOT composite films for DSSCs but does not explore the long-term stability under operational conditions or the scalability of the fabrication process.
1:Experimental Design and Method Selection:
The study involves the synthesis of MoS2 by hydrothermal method and the preparation of PEDOT films via electrochemical polymerization. The composite films are optimized for use as counter electrodes in DSSCs.
2:Sample Selection and Data Sources:
Fluorine-doped tin oxide (FTO) coated conducting glass plates are used as substrates. The materials include sodium molybdate, thiourea, glucose, EDOT, and others.
3:List of Experimental Equipment and Materials:
Equipment includes an autoclave, electrochemical workstation, SEM, TEM, UV-vis spectrometer, and others. Materials include Na2MoO4, CH4N2S, C6H12O6, EDOT, LiClO4, and others.
4:Experimental Procedures and Operational Workflow:
MoS2 is synthesized and spin-coated onto FTO substrates. PEDOT is electrochemically polymerized on MoS2 layers. DSSCs are fabricated and their performance is evaluated.
5:Data Analysis Methods:
The performance of DSSCs is analyzed using J-V curves, cyclic voltammetry, electrochemical impedance spectroscopy, and Tafel polarization tests.
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Ultraviolet?visible absorption spectroscopy
UV-3600
Shimadzu
Measuring transmittance of counter electrodes
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Powder X-ray diffractometer
D/Max 2500
Rigaku
Confirming crystallographic structures of samples
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Field-emission scanning electron microscopy
NanoSEM 450
FEI
Characterizing morphology of counter electrodes
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Transmission electron microscopy
Talos F200X
FEI
Characterizing morphology of samples
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Keithley 2401 source meter
2401
Keithley
Determining photovoltaic performance of DSSCs
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Fluorine-doped tin oxide
FTO
Opvtech
Substrate for counter electrodes
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Raman spectrometer
Invia RM200
Renishaw
Collecting Raman spectra of samples
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Electrochemical workstation
Princeton 4000
Measuring electrocatalytic activity of counter electrodes
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Solar simulator
SXDN-150E
Nowdata
Simulating solar illumination for DSSC testing
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