研究目的
Investigating the luminescent properties of new Dy3+/Eu3+/Sm3+-activated InNbTiO6 phosphors for white UV-LEDs.
研究成果
The Dy3+/Eu3+/Sm3+-activated InNbTiO6 phosphors exhibit promising luminescent properties for UV-LED solid-state lighting devices, with tunable band gaps and characteristic emissions. The phosphors show potential for application in white UV-LEDs due to their quantum yields and thermal stability.
研究不足
The study focuses on the luminescent properties under UV–visible light excitation and does not explore other excitation wavelengths or potential applications beyond UV-LEDs.
1:Experimental Design and Method Selection
The phosphors were synthesized by the conventional solid-state reaction process using stoichiometric amounts of spectral reagents. The mixtures were sintered at 1250°C for 24 h in alumina crucibles.
2:Sample Selection and Data Sources
Samples were prepared with varying concentrations of Dy3+, Eu3+, and Sm3+ dopants. Phase identifications were determined by powder X-ray diffraction (XRD) patterns.
3:List of Experimental Equipment and Materials
In2O3, Nb2O5, TiO2, Dy2O3, Eu2O3, and Sm2O3 with purity higher than 99.99% (Alfa Aesar Company). Equipment includes X-ray diffractometer (Rigaku, D/MAX-2500), UV–visible spectrophotometer (Shimadzu, UV-2450), fluorescence spectrophotometer (Hitachi, F-7000), and fluorescence spectrometer (Edinburgh, FLS-920).
4:Experimental Procedures and Operational Workflow
The mixtures were sintered twice with an intermediate grinding process. XRD, UV-DR, PLE, and PL spectra were recorded, and luminescence decay curves were obtained.
5:Data Analysis Methods
The Rietveld method was used for structure refinement. Band gaps were calculated from UV-DR spectra. Luminescence lifetimes were fitted by a double-exponential decay mode.
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