研究目的
To fabricate high quality single crystalline MAPbI3 nanowires with long carrier life times for high-performance photodetectors.
研究成果
High quality single crystalline MAPbI3 nanowires with a record long carrier life time of 81 ns were successfully fabricated, leading to photodetectors with an extremely low dark current and a high on-off current ratio of 1880. This work contributes to the development of high-performance photodetector devices.
研究不足
The study focuses on MAPbI3 nanowires without exploring other perovskite materials. The photodetector performance could be further optimized by improving the contact barrier between the nanowires and electrodes.
1:Experimental Design and Method Selection:
The surface initiated solution growth strategy was utilized to synthesize single crystalline MAPbI3 nanowires with kinetic control over the growth process.
2:Sample Selection and Data Sources:
Glass substrates were used for the growth of nanowires, with methyl ammonium iodide (MAI) and lead acetate (PbAc2) as precursors.
3:List of Experimental Equipment and Materials:
Optical microscope (Nikon, LV-150), SEM (Hitachi SU3500), XRD (Hao Yuan Instrument, DX-2700), UV-visible absorption spectrometer (Shimadzu, UV-2600), and a home-built fluorescence spectrophotometer system.
4:Experimental Procedures and Operational Workflow:
The growth process included nucleation and growth stages, optimized by controlling temperature and precursor concentration.
5:Data Analysis Methods:
The carrier life time was derived from transient PL spectra using a biexponential function fit.
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