研究目的
To study and fabricate graphene nanowalls/silicon hybrid heterojunction photoconductive detectors to provide process technology and theoretical foundation for the preparation of high-performance photodetectors.
研究成果
The study successfully fabricates GNWs/silicon hybrid heterojunction photodetectors using a novel patterning technology. The photoresponse current of the GNWs/n-Si photoconductive device is highest, and that of the GNWs/p-Si photoconductive device is lowest under low bias VDS. The Schottky barrier height plays a crucial role in determining the photodetection performance. These findings are helpful for the development of future photodetectors with high performance.
研究不足
The study focuses on the fabrication and characterization of GNWs/Si heterojunction photodetectors but does not explore the scalability of the fabrication process or the long-term stability of the devices under operational conditions.
1:Experimental Design and Method Selection:
The GNWs film is patterned by double-layered photoresist-based photolithography and reactive ion etching (RIE) process to achieve high quality GNWs channel. Three different GNWs/Si heterojunction photoconductive detectors with n-doped, intrinsic and p-doped silicon substrates (n-Si, i-Si, p-Si) are fabricated.
2:Sample Selection and Data Sources:
Silicon substrates are annealed at 700 ℃ in H2 for 30 min before growing GNWs. The GNWs film is grown on silicon substrates with the ratio of hydrogen to methane in the flowing mixed gas of 6:4 (sccm) at 750 ℃.
3:List of Experimental Equipment and Materials:
SEM (JEOL JSM-7800F), Raman spectrometer (Renishaw inVia Reflex), AFM (Bruker Dimension Edge?), semiconductor characterization system (Keithley 4200), laser (λ=635 nm).
4:Experimental Procedures and Operational Workflow:
The GNWs film is grown, patterned, and then characterized for morphology and quality. The optoelectronic properties of photoconductive devices are evaluated in dark and light conditions.
5:Data Analysis Methods:
The Schottky barrier height is calculated based on the linearity of dark current experiments using the Schottky diode equation.
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