研究目的
Exploring the effect of growing bulk GaAs crystals with lower purity input materials to reduce their cost and assessing the performance of solar cells grown on these substrates.
研究成果
The use of lower purity metals during GaAs crystal growth does not adversely affect the performance of GaAs solar cells, suggesting a viable pathway for reducing substrate costs.
研究不足
The study focuses on the effect of impurities on GaAs solar cell performance but does not explore the long-term stability or the effect of other types of impurities not tested.
1:Experimental Design and Method Selection:
The study involved growing bulk GaAs crystals by the vertical gradient freeze (VGF) method with intentionally higher impurity concentrations in the melt.
2:Sample Selection and Data Sources:
Two boules of Si-doped GaAs crystals were grown, one with additional impurities (Zn, Cu, Fe) and one as a reference.
3:List of Experimental Equipment and Materials:
Modified single-furnace setup for VGF, glow discharge mass spectroscopy (GDMS), secondary ion mass spectrometry (SIMS), optical microscope for etch pit density (EPD) measurement.
4:Experimental Procedures and Operational Workflow:
Impurities were added to the melt, crystals were grown, wafers were prepared, and solar cells were grown by MOVPE.
5:Data Analysis Methods:
SIMS and GDMS for impurity concentration, EPD for dislocation density, EQE and JV curves for solar cell performance.
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