摘要： In consideration of the unique advantages of new non-fullerene acceptors and the tandem-junction structure, organic photovoltaics (OPVs) based on them are very promising. Studies related to this emerging area began in 2016 with achieved power conversion efficiencies (PCEs) of 8–10%, which have now been boosted to 17%. In this essay, the construction of high-performance OPVs is discussed, with a focus on combining the advantages of new non-fullerene acceptors and the tandem-junction structure. In order to achieve higher PCEs, methods to enable high short-circuit current density, open-circuit voltage, and fill factor are discussed. In addition, the stability and reproducibility of high-efficiency OPVs are also addressed. Herein, it is forecast that the new non-fullerene acceptors-based tandem-junction OPVs will become the next big wave in the field and achieve high PCEs over 20% in the near future. Some promising research directions on this emerging hot topic are proposed which may further push the field into the 25% high efficiency era and considerably advance the technology beyond laboratory research.