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Functionalization of Plastic Parts by Replication of Variable Pitch Laser-Induced Periodic Surface Structures

DOI:10.3390/mi11040429 期刊:Micromachines 出版年份:2020 更新时间:2025-09-23 15:19:57
摘要: Surface functionalization of plastic parts has been studied and developed for several applications. However, demand for the development of reliable and profitable manufacturing strategies is still high. Here we develop and characterize a new process chain for the versatile and cost-effective production of sub-micron textured plastic parts using laser ablation. The study includes the generation of different sub-micron structures on the surface of a mold using femtosecond laser ablation and vario-thermal micro-injection molding. The manufactured parts and their surfaces are characterized in consideration of polymer replication and wetting behavior. The results of the static contact angle measurements show that replicated Laser-Induced Periodic Surface Structures (LIPSSs) always increase the hydrophobicity of plastic parts. A maximum contact angle increase of 20% was found by optimizing the manufacturing thermal boundary conditions. The wetting behavior is linked to the transition from a Wenzel to Cassie–Baxter state, and is crucial in optimizing the injection molding cycle time.
作者: Leonardo Piccolo,Marco Sorgato,Afif Batal,Stefan Dimov,Giovanni Lucchetta,Davide Masato
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To develop and characterize a new process chain for the versatile and cost-effective production of sub-micron textured plastic parts using laser ablation, focusing on the generation of different sub-micron structures on the surface of a mold and their replication through micro-injection molding.

The study successfully developed a process chain for the cost-effective production of sub-micron textured plastic parts using laser ablation and micro-injection molding. The results show that the presence of a pattern increases surface functionality, with maximum water contact angle increases of 20% and 17% for PMMA and PS samples, respectively. The functionalization was affected by the polymer temperature, depending on melt viscosity. The findings suggest that keeping a lower mold temperature leads to a decrease in manufacturing costs both from energy consumption and cycle time savings.

The study is limited to the use of specific polymers (PS and PMMA) and does not explore the full range of potential materials. The laser texturing process, while fast, may have limitations in terms of the uniformity and depth of structures achievable at higher beam incidence angles. The replication accuracy and functionalization are highly dependent on mold temperature, which may limit the process's applicability in scenarios where temperature control is challenging.

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