研究目的
Investigating the effects of tin doped indium oxide (ITO) thin films with different thicknesses on the optoelectronic performance and the performance of CZTS solar cells.
研究成果
The study concluded that ITO films with a thickness of 383 nm exhibited optimal optoelectronic properties, leading to significant improvements in the performance of CZTS solar cells. The findings suggest an optimal ITO layer thickness range for high-efficiency CZTS solar cells.
研究不足
The study was limited to ITO films with thicknesses ranging from 50 nm to 476 nm and annealed at a fixed temperature of 180°C. The impact of other annealing conditions or deposition methods was not explored.
1:Experimental Design and Method Selection:
The study involved the deposition of ITO films with varying thicknesses (50 nm–476 nm) using RF magnetron sputtering and annealing at 180°C for 60min under air atmosphere. The optoelectronic properties of these films were then analyzed.
2:Sample Selection and Data Sources:
ITO films were prepared on SLG substrates. The thicknesses were varied by adjusting the sputtering time.
3:List of Experimental Equipment and Materials:
Equipment included RF-magnetron sputtering for ITO deposition, X-ray diffraction (XRD) for crystal structure analysis, FE-SEM for surface morphology, UV–Vis–NIR spectroscopy for optical reflectance, and Hall System for electrical properties measurement.
4:Experimental Procedures and Operational Workflow:
The process involved sputtering ITO layers on SLG substrates, annealing, and then characterizing the films for structural, optical, and electrical properties. The ITO layers were then applied in CZTS solar cells to study their impact on performance.
5:Data Analysis Methods:
The data were analyzed to determine the relationship between ITO film thickness and optoelectronic properties, as well as the performance of CZTS solar cells.
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X-ray diffraction
Rigaku Ultima IV multipurpose
Rigaku
Examining the crystal structures of ITO film
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Field emission scanning electron microscope
Zeiss SUPRA 55 VP
Zeiss
Characterizing the surface morphology of ITO films
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Energy Dispersive Spectrometer
Oxford Instrument X-MaxN
Oxford Instrument
Analyzing the composition of ITO films
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Hall System
Nanometrics HL5500
Nanometrics
Analyzing the electrical performances of ITO films
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Source Meter
keithley 2400
keithley
Measuring current density-voltage (J-V) characteristics of the CZTS devices
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UV–Vis–NIR spectroscopy
UV-3600
Estimating the optical reflectance spectra of films
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Step profiler
Dektak 150
Measuring the thicknesses of ITO films
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Solar simulator
1.5 global spectrum (AM1.5G)
Simulating solar conditions for testing solar cells
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