研究目的
Investigating the stability and scalability of inorganic halide perovskites for wavelength-conversion and lasing applications.
研究成果
The study demonstrates ultrastable wavelength-converting and lasing action from wafer-scale CsPbBr3 perovskites. The surface defects block the optical amplification from the bulk crystal, but robust stimulated emission by TPA in the near infrared regime could take place. The defective surface serves as an effective protecting layer for the perovskite wafer, enabling long-term-stable gain without any encapsulation.
研究不足
The study focuses on the stability and scalability of inorganic halide perovskites for wavelength-conversion and lasing applications, but does not address potential environmental or health impacts of the materials used.
1:Experimental Design and Method Selection:
The study employs wafer-scale inorganic perovskite single crystals for wavelength-conversion and optical gain. Spectroscopic analysis is used to investigate carrier trapping and optical amplification.
2:Sample Selection and Data Sources:
CsPbBr3 perovskite wafer was grown by the modified vertical Bridgman technique.
3:List of Experimental Equipment and Materials:
CsPbBr3 wafer, optical cavities made by two mirrors paralleling to each other.
4:Experimental Procedures and Operational Workflow:
The photoluminescence under excitation in near infrared region was investigated. The pump-fluence dependent PL spectra under focused pump beam at optical wavelength of 800 nm are shown.
5:Data Analysis Methods:
The PL intensity under one-photon excitation and two-photon excitation as a function of photon-generated carrier density is analyzed to reveal the trap density at the surface and interior of the crystal.
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