研究目的
Investigating the influence of the nonlocal effect on the optical properties of nonspherical plasmonic semiconductor nanoparticles, specifically focusing on TiN and ZrN as alternative plasmonic materials to noble metals.
研究成果
The research demonstrates that ZrN exhibits a more pronounced plasmon resonance than TiN, with the nonlocal effect leading to a plasmon resonance blue shift and damping similar to noble metals. Smaller particles show a larger influence of the nonlocal effect than larger ones. The study also highlights the significant impact of polarization on the optical responses of nonspherical particles, with ZrN particles showing more pronounced extinction than gold particles of the same size and shape.
研究不足
The study is computational, relying on theoretical models and simulations, which may not fully capture all physical phenomena in real-world applications. Experimental validation is suggested for future work to confirm the theoretical findings.
1:Experimental Design and Method Selection:
The study employs the discrete sources method (DSM) extended to incorporate the hydrodynamic Drude model (HDM) for analyzing the nonlocal effect (NLE) on the optical characteristics of semiconductor nanoparticles.
2:Sample Selection and Data Sources:
The research focuses on metal nitrides TiN and ZrN as nanoparticle materials, comparing their optical properties with those of gold (Au).
3:List of Experimental Equipment and Materials:
The study involves computational simulations without specifying physical equipment, utilizing parameters from the Drude–Lorentz model for dielectric function simulation.
4:Experimental Procedures and Operational Workflow:
The methodology includes constructing approximate solutions for scattering problems using DSM for different polarizations, analyzing the impact of particle deformation on optical properties, and comparing results with and without accounting for NLE.
5:Data Analysis Methods:
The analysis involves evaluating the extinction cross-section and far field pattern components for spherical and spheroidal particles under various conditions.
独家科研数据包,助您复现前沿成果,加速创新突破
获取完整内容