研究目的
To unravel the roles of mesoporous TiO2 frameworks in CH3NH3PbI3 perovskite solar cells (PSCs) by comparing the properties of perovskite films and the device performances for both planar and mesoporous architectures.
研究成果
The presence of mesoporous TiO2 layer in PSCs offers several advantages, including enlarged perovskite crystal grains, enhanced light harvesting, efficient interface charge extraction, and effective suppression of charge recombination. These benefits lead to improved device performance with higher power conversion efficiency and reduced hysteresis.
研究不足
The study focuses on CH3NH3PbI3 PSCs, and the findings may not be directly applicable to other perovskite materials or architectures. The research also highlights the need for further understanding of the grain growth dynamic process of perovskite materials.
1:Experimental Design and Method Selection:
The study involved the fabrication of both planar and mesoporous PSCs, followed by detailed characterizations of structural, microscopic, optical, and electrical properties.
2:Sample Selection and Data Sources:
The samples were prepared using fluorine-doped tin oxide glass (FTO) as the substrate, with perovskite films fabricated via a one-step method.
3:List of Experimental Equipment and Materials:
Included FTO, TiO2 paste (Dyesol 18NR-T), perovskite precursor solutions, and various characterization tools like XRD, SEM, UV-vis-NIR spectrophotometer, PL spectra, and FLIM system.
4:Experimental Procedures and Operational Workflow:
The fabrication process involved spin-coating of TiO2 layers, deposition of perovskite films, and the application of hole transporting layers and Ag electrodes.
5:Data Analysis Methods:
The data were analyzed using various techniques to assess the performance and properties of the PSCs.
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X-ray diffractometer
X’Pert PRO MPD
Panalytical B. V.
Used for structural characterization of the perovskite films.
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Field emission scanning electron microscope
JSM-6700F
JEOL
Used for microscopic characterization of the films.
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UV-vis-NIR spectrophotometer
CARY 5000
Agilent
Used for optical absorption measurements.
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TiO2 paste
Dyesol 18NR-T
Dyesol
Used as the mesoporous electron transporting layer in perovskite solar cells.
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FTO glass
Used as the transparent conducting substrate for the solar cells.
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Photoluminescence spectrometer
Used for PL spectra recording.
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Fluorescence-lifetime imaging microscopy system
PZ-FLIM-110
Used for time-resolved PL measurements.
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Solar simulator
Oriel Sol 3A
USA
Used for J-V curve measurements under simulated sunlight.
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Electrochemical workstation
Zennium Pro.
Zahner
Used for IPCE and EIS measurements.
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