研究目的
To optimise the conditions for the biosynthesis of monodispersed silver nanoparticles using Morti?o berry extract as reductant and capping agent, and to evaluate their photocatalytic activity against methylene blue dye.
研究成果
The study successfully demonstrated the ecofriendly synthesis of monodispersed silver nanoparticles using Morti?o berry extract, with an average size of 20.5 ± 1.5 nm. The nanoparticles exhibited photocatalytic activity against methylene blue dye, suggesting potential applications in water treatment and environmental remediation.
研究不足
The study is limited to the use of Morti?o berry extract for the synthesis of silver nanoparticles and their photocatalytic activity against methylene blue dye. The scalability and industrial applicability of the method were not explored.
1:Experimental Design and Method Selection:
The synthesis of silver nanoparticles was optimised by adjusting the amount of berry extract, pH, and time. The biosynthesis was confirmed by UV-visible spectroscopy.
2:Sample Selection and Data Sources:
Fresh Morti?o berries were used to prepare the extract. Silver nitrate and methylene blue dye were used as precursors.
3:List of Experimental Equipment and Materials:
Silver nitrate (AgNO3), methylene blue (MB), gallic acid, Folin-Ciocalteu′s phenol reagent, Whatman No.1 paper, rotary evaporator, lyophiliser, UV-visible spectrophotometer, TEM, DLS, XRD.
4:Experimental Procedures and Operational Workflow:
The extract was prepared by soaking crushed berries in ethanol/water solution, filtered, and lyophilised. Silver nanoparticles were synthesised by adding the extract to AgNO3 solution under visible light, adjusting pH, and incubating at room temperature. The nanoparticles were characterised by TEM, DLS, and XRD. Photocatalytic activity was evaluated by degrading MB dye under sunlight.
5:Data Analysis Methods:
The photocatalytic degradation efficiency was calculated using UV-vis spectroscopy, and the rate constant was determined using first-order kinetics.
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Folin-Ciocalteu′s phenol reagent
FC
Sigma-Aldrich
Reagent for total polyphenolic content estimation
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UV-visible spectrophotometer
SPECORD ? S600
Analytik Jena
Measurement of absorbance for nanoparticle synthesis confirmation and photocatalytic activity evaluation
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Dynamic light scattering
HORIBA LB-550
HORIBA
Hydrodynamic size distribution analysis of nanoparticles
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Transmission electron microscopy
FEI Tecnai, G2 Spirit Twin
FEI
Morphology and size analysis of nanoparticles
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X-ray diffraction
XRD EMPYREAN
PANalytical
Crystalline nature analysis of nanoparticles
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Silver nitrate
AgNO3
Spectrum
Precursor for the synthesis of silver nanoparticles
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Methylene blue
MB
Spectrum
Model dye for photocatalytic degradation study
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Gallic acid
Sigma-Aldrich
Standard for total polyphenolic content estimation
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pH meter
Seven Easy pH
METTLER TOLEDO
pH measurement of solutions
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