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Cu2O photocatalyst modified antifouling polysulfone mixed matrix membrane for ultrafiltration of protein and visible light driven photocatalytic pharmaceutical removal

DOI:10.1016/j.seppur.2018.11.029 期刊:Separation and Purification Technology 出版年份:2018 更新时间:2025-09-23 15:21:21
摘要: This study explains synthesis, characterization of an effective and efficient mixed matrix polysulfone (PSF) ultrafiltration membrane modified with Cu2O photocatalyst, synthesized using electrodeposition method, for pharmaceutical removal. Cu2O photocatalyst, polyethylene glycol, and N-methyl-2-pyrrolidone were used as additive, pore former, and solvent, respectively in the phase inversion method. Characterization techniques, such as XRD, FTIR, FESEM, FESEM-EDX, and AFM were used to characterize the photocatalyst and blended membranes so as to analyze their structural and functional attributes. Further, the membranes were analyzed by using permeation techniques to analyze their flux profiles. Similarly, antifouling nature and hydrophilicity of the membranes were studied by permeating aqueous BSA solutions and measuring the static water contact angle (SWCA), respectively. The pharmaceutical removal studies were carried out using ibuprofen (IBP). The additive improves the membrane attributes, such as flux improved from 34.24 L m-2 h-1 to 179.54 L m-2 h-1 deciphering improved porosity and pore size distribution; SWCA decreased from 71.5° to 45.3° showing increase in the hydrophilicity of the membranes; BSA adsorption decreased from 56 μg cm-2 to 27 μg cm-2; and successful removal of IBP at 86% was achieved under visible light conditions with a removal rate of 32.63 × 10-3 min-1.
作者: Randeep Singh,V.S.K. Yadav,Mihir Kumar Purkait
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The objectives of this study were preparation of Cu2O modified PSF MMM by using phase inversion technique and characterization using Field emission electron microscopy (FESEM), atomic force microscopy (AFM), Fourier transform infrared spectroscopy (FTIR), and FESEM-EDX. Also, the flux profile, hydrophilicity, antifouling performance, and protein separation were analyzed by measuring membranes pure water flux (PWF), water contact angle (WCA), and BSA permeation. Lastly, the photocatalytic removal of IBP is carried out, under dark and visible conditions, using the prepared membranes.

Cu2O photocatalyst modified mixed matrix PSF ultrafiltration membranes were successfully synthesized and shown to be effective for the removal of IBP under visible light. The membranes exhibited improved hydrophilicity, antifouling nature, and photocatalytic activity, making them promising for pharmaceutical removal applications.

The study focuses on the removal of a single pharmaceutical (IBP) and may not be directly applicable to other pharmaceuticals without further research. The long-term stability and scalability of the membranes for industrial applications were not extensively studied.

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