研究目的
Investigating the photocatalytic degradation of toxic medical and textile dyes using ZnO quantum dots and ZnO/rGO composites under UV irradiation.
研究成果
The ZnO/rGO composite, especially with a 3:1 wt ratio of ZnO to rGO, demonstrated superior photocatalytic activity, degrading almost 100% of the tested dyes within 15 to 30 minutes under UV irradiation. This is attributed to the efficient charge transfer from rGO to ZnO, reducing electron-hole recombination and enhancing photocatalytic efficiency.
研究不足
The study focuses on UV light-induced photocatalytic degradation, which may not be as efficient under visible light. The scalability and cost-effectiveness of the solvothermal method for large-scale applications are not addressed.
1:Experimental Design and Method Selection:
ZnO QD was synthesized via a soft chemical route followed by ageing, and ZnO/rGO composites were prepared using a solvothermal method.
2:Sample Selection and Data Sources:
The study used Safranin O, Methylene blue, and Rhodamine 6G dyes for photocatalytic degradation tests.
3:List of Experimental Equipment and Materials:
Included X-ray diffractometer (X'Pert Pro), transmission electron microscopy (JEOL JEM 2100 HR with EELS), Raman spectrometer (Lab RAM HR Jovin Yvon), UV/VIS Spectrometer (Perkin Elmer Lambda 25), and fluorescence spectrometer (Horiba FL 1000).
4:0). Experimental Procedures and Operational Workflow:
4. Experimental Procedures and Operational Workflow: Photocatalytic activity was measured using a home-made system with a 100 W UV lamp, monitoring dye degradation over time.
5:Data Analysis Methods:
The photocatalytic degradation followed pseudo first-order kinetics, analyzed using UV/Vis absorption spectra.
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