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Cataluminescence sensor for highly sensitive and selective detection of iso-butanol

DOI:10.1016/j.talanta.2018.11.016 期刊:Talanta 出版年份:2018 更新时间:2025-09-23 15:21:21
摘要: In this paper, a gaseous sensor was described for detection of iso-butanol on the basis of its strong cataluminescence (CTL) emission on nano-MgO surface. The sensor showed high sensitivity and specificity to iso-butanol with response time less than 1 s and recovery time less than 18 s. A good linearly relationship between CTL intensity and the concentration of iso-butanol was observed in the range of 7.6 to 3350 mg/m3 (r = 0.9992), the limit of detection was 2.5 mg/m3. The proposed CTL sensor exhibits good specificity to iso-butanol against other compounds including common alcohols. The possible reaction paths of iso-butanol on the MgO surface were investigated in detail. Results shows that the hydrogen atom abstraction of iso-butanol to form β-Riso following consumption via Waddington mechanism possible is a major reaction channel for CTL emission. The sensor was applied to analyze iso-butanol in spiked samples, satisfactory recoveries were obtained in the range of 96.6 to 112.8% and the RSDs were 5.0 to 10.1%, indicating that the proposed sensor is a promising candidate for rapid analysis of iso-butanol.
作者: Feifei Meng,Zhenyu Lu,Runkun Zhang,Gongke Li
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The rapid advances in industry and development of society results in the air pollution becomes a serious environmental issue affecting human health. Volatile organic compounds (VOCs) are identified as the main origin of pollutions in the air, due to many of them can be toxic or carcinogenic even at low concentrations. The monitoring of VOCs concentration is of significant important to environmental monitoring and to human health. Methods based on gas chromatograph and gas chromatograph/mass spectrometer are widely used for the analysis of VOCs. However, the instruments of these methods used are bulky, expensive, and unsuitable for real-time, in-situ monitoring. In recent years, gas sensors have received much attention and interest because they are capable of real-time measurement of temporal change in VOC concentrations, which can provide timely results in the actual locale for the evaluation of the potential hazards of VOCs.

In summary, a gas sensor for iso-butanol was developed based on the CTL emission during the catalytic oxidation of iso-butanol on MgO surface. The sensor exhibits high sensitivity and good specificity to iso-butanol. The possible mechanism behind the CTL emission of iso-butanol on MgO surface was investigated. The sensor was applied to the determination of iso-butanol in spiked samples, satisfactory results were obtained. The proposed sensor offers a sensitive, selective and convenient way for the rapid monitoring of iso-butanol, it can be potentially applied in environment and industry grounds.

The technical and application constraints of the experiments, as well as potential areas for optimization, were not explicitly mentioned in the paper.

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