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Highly sensitive air stable easily processable gas sensors based on Langmuir-Schaefer monolayer organic field-effect transistors for multiparametric H <sub/>2</sub> S and NH <sub/>3</sub> real-time detection

DOI:10.1021/acsami.8b15427 期刊:ACS Applied Materials & Interfaces 出版年份:2018 更新时间:2025-09-11 14:15:04
摘要: A combination of low limit of detection, low power consumption and portability makes organic field-effect transistors (OFETs) chemical sensors promising for various applications in the areas of industrial safety control, food spoilage detection and medical diagnostics. However, the OFET sensors typically lack air stability and restoration capability at room temperature. Here we report on a new design of highly sensitive gas sensors based on Langmuir-Schaefer monolayer organic field-effect transistors (LS OFETs) prepared from organosilicon derivative of [1]benzothieno[3,2-b][1]-benzothiophene. The devices fabricated are able to operate in air and allows an ultrafast detection of different analytes at low concentrations down to tens ppb. The sensors are reusable and can be utilized in real-time air quality monitoring systems. We show that a direct current response of the LS OFET can be splitted into the alteration of various transistor parameters, responsible for the interactions with different toxic gases. The sensor response acquiring approach developed allows distinguishing two different gases, H2S and NH3, with a single sensing device. The results reported open new perspectives for the OFET-based gas-sensing technology and pave the way to easy detection of the other types of gases enabling the development of complex air analysis systems based on a single sensor.
作者: Alexey S. Sizov,Askold A. Trul,Viktoriya Chekusova,Oleg V. Borshchev,Alexey A. Vasiliev,Elena V. Agina,Sergei A. Ponomarenko
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To design and realize highly sensitive gas sensors based on Langmuir-Schaefer monolayer organic field-effect transistors (LS OFETs) for the detection of toxic gases like H2S and NH3 at low concentrations down to tens ppb, with the ability to operate in air and be reusable in real-time air quality monitoring systems.

The LS OFETs based on organosilicon dimer of dialkyl-BTBT O(Si-Und-BTBT-Hex)2 are capable of operating in air and detecting H2S and NH3 at low concentrations. The sensors are reusable and can distinguish between different gases based on variations in transistor parameters. This opens new perspectives for OFET-based gas-sensing technology.

The study focuses on the detection of H2S and NH3, and the mechanisms for other gases may differ. The devices require specific conditions for optimal performance, such as dry air for some measurements.

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