摘要： The small energy difference between the fundamental level and the first opposite parity configuration of Pr3+-doped hosts is particularly challenging for the characterization of radiative transitions using the Judd-Ofelt theory, although modified versions of the theory have been proposed in the past for the investigation of praseodymium doped materials. Here, we present a detailed spectroscopic investigation on two sets of calcium aluminosilicate glasses, with 34 wt.% of SiO2 (CAS) and with 7 wt.% of SiO2 (LSCAS), doped with different concentrations of Pr3+ (0.5, 1.0 and 2.0 wt.%). We use the standard Judd-Ofelt theory to characterize the glasses and the results and derived spectroscopic quantities — such as transition probabilities, radiative lifetimes and branching ratios — are compared to results obtained by the modified Judd-Ofelt theories. The analysis showed that the modified theories could lead to smaller values of root mean square deviations. However, a better agreement between experimental data and the standard theory was achieved when the derived spectroscopic quantities are taken into account. Moreover, the branching ratios of the 3P0 → 3H4 and 1D2 → 3H4 transitions were over 60% for both glass hosts, suggesting its potential use as solid-state laser devices.