研究目的
To discover new materials with good mid?infrared (MIR) nonlinear optical (NLO) performances, focusing on Ag4P2Se6 as a potential candidate due to its structural diversities and strong covalent P?Q bonds.
研究成果
Ag4P2Se6 exhibits a moderate SHG response with phase matching ability and a higher LDT than AgGaS2, along with a low melting temperature and excellent chemical stability, making it a promising material for MIR?NLO applications.
研究不足
The study is limited to the evaluation of Ag4P2Se6's SHG property and LDT, with potential for further exploration of other ternary thiophosphates and selenophosphates.
1：Experimental Design and Method Selection:
The study involved the synthesis of Ag4P2Se6 crystals via high?temperature solid state reaction, followed by characterization of their SHG properties and LDT.
2：Sample Selection and Data Sources:
Polycrystalline samples were synthesized from Ag, P, and Se.
3：List of Experimental Equipment and Materials:
Equipment included a XPERT?MPD θ?2θ diffractometer, NETZSCH STA 449F3 unit, PE Lambda 950 spectrophotometer, and VERTEX 70 FTIR spectrophotometer.
4：Experimental Procedures and Operational Workflow:
The synthesis involved heating a mixture of Ag, P, and Se in a quartz tube under vacuum, followed by characterization techniques.
5：Data Analysis Methods:
The SHG response was measured using a modified method of Kurtz and Perry, and LDT was measured using a single?pulse measurement method.
独家科研数据包，助您复现前沿成果，加速创新突破
获取完整内容
