摘要： By using the one-dimensional tight-binding model, we theoretically investigate the effect of magnetic field on the collision of the oppositely charged polarons with their spin antiparallel in cis-polyacetylene. We adopt the non-adiabatic approach to simulate the dynamical evolution of polaron spin. Under the effect of electric field with a moderate strength, the polarons initially localized at the chain-end of polyacetylene move towards each other. During the collision process, an obvious spin precession is obtained, and the precession period is found to be inversely proportional to the strength of magnetic field. While after including electron-electron interaction in form of Hubbard model, the period is no longer constant. With the decrease of distance between the oppositely charged polarons, the precession of their spin slows down. We also find that there is a critical value of electron-electron interaction strength, over which the spin precession of polaron disappears. In addition, we demonstrate that under the effect of magnetic field, the polarons could recombine or pass through each other to form the singlet exciton, rather than be dissociated after collision between them with the strong electron-electron interaction, and then the electroluminescence efficiency of organic optoelectronic devices is improved.