研究目的
Investigating the effect of single-walled carbon nanotubes on the growth dynamics and helicity of B7 helical filaments formed from bent-core mesogens.
研究成果
The addition of single-walled carbon nanotubes to the B7 phase results in slightly tighter filament structures with decreased growth velocities, suggesting nanotubes act as nucleation sites. The periodicity of the helical structure remains unaffected, indicating the intrinsic nanotube chirality does not influence the filament chirality. The observed buckling instability provides a model system for studying nonlinear dynamics of filaments, with potential applications in biomolecular ordering and high tensile strength fibres.
研究不足
The study is limited to observations at a constant quench depth in thermodynamic equilibrium. The effect of varying cooling rates or non-equilibrium conditions was not investigated. Additionally, the chirality of individual nanotubes and its potential influence on the filament chirality was not explored due to the arbitrary handedness of nanotube bundles.
1:Experimental Design and Method Selection:
The study involves the observation of B7 phase filament growth from the isotropic melt in the presence of single-walled carbon nanotubes (SWCNT). Polarizing optical microscopy (POM) was used to observe the growth dynamics and structural features of the filaments.
2:Sample Selection and Data Sources:
The bent-core material used is a typical banana-shaped compound with a specific structural formula. SWCNT were commercially available and used as received. Samples were prepared at varying concentrations of nanotubes.
3:List of Experimental Equipment and Materials:
Leica OPTIPHOT polarizing optical microscope, Linkam hot stage (LTS350) and temperature controller (TP94), uEye digital camera for image acquisition, ImageJ software for analysis.
4:Experimental Procedures and Operational Workflow:
Samples were cooled at a rate of 0.1Kmin-1 to observe the isotropic to B7 phase transition. Movies of the growth process were acquired for further analysis.
5:1Kmin-1 to observe the isotropic to B7 phase transition. Movies of the growth process were acquired for further analysis.
Data Analysis Methods:
5. Data Analysis Methods: The growth velocity and filament width were determined from the acquired images. The periodicity of the helical superstructure was also analyzed.
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