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Nanoscale Materials in Water Purification || Photocatalysis of Graphene and Carbon Nitride-Based Functional Carbon Quantum Dots

DOI:10.1016/b978-0-12-813926-4.00035-5 出版年份:2019 更新时间:2025-09-09 09:28:46
摘要: Day by day, global energy demands increase due to the rapid consumption of depleting fossil fuels and environmental pollution. This has led to the search for materials capable of both energy conversion and elimination of environmental pollutants through the aid of renewable solar energy. This is a promising approach for meeting future energy requirements and eliminating environmental pollutants. In this pursuit, semiconductor photocatalysts have immense potential for solving both energy and environmental issues. To date, numerous semiconductor materials have been explored, including those of metal oxides, chalcogenides, borates, titanates, tungstates, vanadates, zirconates, oxyhalides, and metal-based interstitial compounds. However, the majority of these suffer from limitations such as complex synthesis procedures, limited light absorption range due to their wide band gap, high cost, and toxicity-related issues. Over the past decade, carbon-based nanomaterials have gained attention in the field of photocatalysis. Many recent articles have placed emphasis upon metal-free carbon-based photocatalytic systems for degradation of organic pollutants and hydrogen production from water splitting. The prime merit of these nanomaterials is that they originate from naturally abundant constituent elements such as carbon, nitrogen, and oxygen, making them more economical than their metal-based counterparts. Most reported carbon-based photocatalysts have tunable band gap energies, enhancing their optical absorption range. Band gap energy can be tuned by varying synthesis conditions and precursors, resulting in the formation of nanomaterials with different morphologies. The preparation procedures for most carbon-based nanomaterials are less complex than those of metal-based materials.
作者: Amit Mishra,Soumen Basu,Nagaraj P. Shetti,Kakarla Raghava Reddy,Tejraj M. Aminabhavi
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Investigating the photocatalytic effects of graphene and carbon nitride-based functional carbon quantum dots on energy conversion and the elimination of environmental pollutants.

The study concludes that carbon-based quantum dots like GQDs and GCNQDs are promising candidates for photocatalytic applications due to their low cost, low toxicity, and tunable band gaps. They enhance the photocatalytic performance of semiconductors for wastewater treatment and hydrogen production. However, challenges such as dependency on noble metals and limited light absorption range need to be addressed for practical applications.

The limitations include the dependency on noble metal cocatalysts for high hydrogen production yield, which increases the cost. The efficiency of carbon-based quantum dots in the blue/green region limits their light-harvesting capability. The overall efficiency of these materials for water splitting is still low, and the photoluminescence upconversion efficiency needs improvement.

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