摘要： Oriented hierarchical fibrous-like ZnO nanowires with the diameter of about 30–50 nm and the length of about 15–30 um were successfully synthesized on the seed-coated Zn substrates by a simple two-step process. The morphology and structure of the obtained samples were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), and transmission electron microscopy (TEM). It is shown that fibrous-like ZnO nanowires with the aspect ratio of about 500～1000 present the dense reticular structure, which are grown on ZnO nanowire arrays. But beyond that, as-prepared samples are found to be good single crystalline with hexagonal wurtzite structure and preferential grow along the c-axis. A possible growth mechanism of oriented hierarchical fibrous-like ZnO nanowires is presented in detail, revealing that the synthesis of fibrous-like ZnO nanowires should be attributed to differences in the growth rate of the different crystallographic planes and the two growth ways. The photoluminescence (PL) spectra of oriented hierarchical fibrous-like ZnO nanowires grown at 240 min shows the 5 nm blue-shift and enhanced intensity property in the UV emission.