研究目的
Investigating the applicability of Dy-doped yttrium aluminum garnet (YAG:Dy) in phosphor thermometry at different oxygen concentrations.
研究成果
YAG:Dy is sensitive to oxygen concentration for determining the intensity ratio and lifetime, especially above 1000 K. The intensity ratios and lifetimes of YAG:Dy depend on the oxygen concentration, indicating that oxygen concentration is an important parameter for achieving high-precision measurements in phosphor thermometry.
研究不足
The study highlights the sensitivity of YAG:Dy to oxygen concentration, especially above 1000 K, which could limit its applicability in environments with varying oxygen levels. The response time for oxygen quenching and the reduction in intensity caused by oxygen quenching are also discussed as potential limitations.
1:Experimental Design and Method Selection:
The study utilized a third-harmonic Nd:YAG laser to excite the YAG:Dy phosphor sample. Phosphorescence was measured using a photomultiplier tube for lifetime detection and a spectrometer for intensity ratio detection between two emission lines.
2:Sample Selection and Data Sources:
Dy-doped YAG phosphor was prepared by the sol–gel method.
3:List of Experimental Equipment and Materials:
Equipment included a quartz pipe chamber, tubular electric furnace, K-type thermocouple, PID temperature control unit, mass flow controllers, Nd:YAG laser, photomultiplier tube, spectrometer, and various optical filters.
4:Experimental Procedures and Operational Workflow:
The phosphors were excited at 355 nm, and phosphorescence was measured at temperature intervals from room temperature to 1273 K under controlled oxygen concentrations.
5:Data Analysis Methods:
The intensity ratios and lifetimes were analyzed to assess the effects of temperature and oxygen concentration on phosphorescence.
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Nd:YAG laser
Q-Smart 850
Quantel
Excitation of the YAG:Dy phosphor sample at 355 nm
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Photomultiplier tube
H10721-210
Hamamatsu
Detection of phosphorescence for lifetime measurement
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Spectrometer
USB2000+
Ocean Optics
Detection of the intensity ratio between two emission lines
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Tubular electric furnace
ARF-40K
Asahi
Heating the phosphors in the quartz pipe chamber
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PID temperature control unit
PAC16 and SR91
Shimaden
Controlling the temperature of the furnace
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