研究目的
Investigating the photocatalytic performance of TiO2, N,TiO2, Pt, N-TiO2, N-TiO2-rGO, and Pt, N-TiO2-rGO samples for hydrogen production under visible light.
研究成果
The PNTRG sample exhibited the highest photocatalytic activity for hydrogen production under visible light, attributed to the hindered recombination rate of photoinduced holes and electrons, increased reactant adsorption, and shifting of the band gap energy to the visible region. The photocatalyst was stable for five hydrogen production cycles.
研究不足
The study focuses on the photocatalytic performance under visible light and the stability for hydrogen production cycles, but does not explore the scalability or economic feasibility of the synthesis process.
1:Experimental Design and Method Selection:
A hydrothermal technique was applied for the preparation of nitrogen-doped titania-reduced graphene oxide (NTRG) and platinum-nitrogen-codoped titania-reduced graphene oxide (PNTRG).
2:Sample Selection and Data Sources:
Samples were characterized using PL, UV–Vis, XRD, BET, TEM, and photocurrent testing.
3:List of Experimental Equipment and Materials:
JEOL-JEM-1230 TEM, Chromatech Nova 2000 instrument, Bruker axis D8 XRD instrument, Shimadzu RF-5301 fluorescence spectrophotometer, V-570, Jasco, Japan apparatus, Zahner Zennium electrochemical workstation, Agilent GC 7890A system.
4:Experimental Procedures and Operational Workflow:
The photocatalytic activity was measured using a typical water splitting photocatalytic setup under visible light.
5:Data Analysis Methods:
The characterization results were analyzed to understand the photocatalytic performance and stability of the samples.
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JEOL-JEM-1230 TEM
JEM-1230
JEOL
Examination of the sample morphology
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Bruker axis D8 XRD instrument
D8
Bruker
Crystal structure investigation
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Shimadzu RF-5301 fluorescence spectrophotometer
RF-5301
Shimadzu
Photoluminescence emission spectra determination
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V-570, Jasco, Japan apparatus
V-570
Jasco
Band gap energy determination
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Agilent GC 7890A system
7890A
Agilent
Hydrogen evolved concentration measurement
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Chromatech Nova 2000 instrument
Nova 2000
Chromatech
Texture properties investigation
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Zahner Zennium electrochemical workstation
Zennium
Zahner
Photocurrent intensity determination
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