研究目的
To review recent developments in multinuclear 1,3-P,N-ligand-stabilized complexes, with a shift from applications in catalysis to photoluminescence, covering the period from 2009 to mid-2017.
研究成果
Recent investigations show a shift from catalysis to photophysical studies in multinuclear 1,3-P,N-ligand chemistry, with coinage metals enabling photoluminescent complexes. Ligand tuning allows control over emissive behavior, and concepts from mononuclear catalysis can be adapted for cluster catalysis.
研究不足
The review excludes systems with unavailable donors, additional donor atoms, or conformationally restricted ligands not comparable to 1,3-P,N-ligands. It is limited to literature from 2009 to mid-2017 and does not include original experimental data or new methodologies.
