研究目的
To study the fabrication and properties of Er3+-doped zinc silicate glass-ceramics using waste glass bottles for potential application in optoelectronic devices.
研究成果
The research successfully fabricated Er3+-doped zinc silicate glass-ceramics with enhanced green photoluminescence, indicating potential for optoelectronic applications. Future studies could focus on scaling up production and testing in actual devices.
研究不足
The study is limited to specific Er2O3 concentrations (0-5 wt.%) and heat treatment conditions (900°C for 2 hours). Potential optimizations could include varying other parameters like temperature or time, and exploring other rare earth dopants or waste sources.
1:Experimental Design and Method Selection:
Conventional melting and quenching method was used to synthesize glass-ceramics samples with different Er2O3 doping concentrations (0-5 wt.%). The rationale was to investigate the effect of erbium oxide on physical, structural, and optical properties.
2:Sample Selection and Data Sources:
Samples were prepared from SLS waste glass powder, ZnO (
3:99% purity), and Er2O3 (99% purity). Selection criteria included varying Er2O3 content. List of Experimental Equipment and Materials:
Alumina crucible, electrical furnace, polyvinyl alcohol (PVA) binder, Philips X'pert PRO PW 3040 MPD XRD, FEI NOVA NanoSEM 230 Series FESEM, Perkin Elmer Spectrum 100 Series FTIR spectrophotometer, Perkin Elmer Lambda 35 UV-visible spectrophotometer, Perkin Elmer LS 55 Fluorescence spectrometer. Materials included SLS waste glass, ZnO, Er2O3, PVA.
4:Experimental Procedures and Operational Workflow:
Mixtures were melted at 1400°C for 2 hours, quenched in water, crushed to powder, pressed into pellets with PVA binder, and heat-treated at 900°C for 2 hours. Characterizations included density measurement, XRD, FESEM, FTIR, UV-visible absorption, and photoluminescence.
5:Data Analysis Methods:
Density calculated using Archimedes principle, optical band gap determined from UV-visible data using direct forbidden transition equation, emission spectra analyzed for intensity and wavelength.
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Field emission scanning electron microscopy
NOVA NanoSEM 230 Series
FEI
Observe the surface morphology of glass-ceramics samples
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Fourier transform infrared spectroscopy
Spectrum 100 Series
Perkin Elmer
Verify the functional group or chemical bonding of glass-ceramics samples
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UV-visible spectrophotometer
Lambda 35
Perkin Elmer
Analyze absorption spectra and measure optical band gap
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Fluorescence spectrometer
LS 55
Perkin Elmer
Record emission spectra photoluminescence
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X-ray diffraction
X'pert PRO PW 3040 MPD
Philips
Analyze the crystal structure of glass-ceramics samples
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Zinc oxide
Alfa Aesar
Raw material for synthesis
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Erbium oxide
Alfa Aesar
Dopant for enhancing luminescence
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