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Improved galvanic porous silicon fabrication using patterned electrodes

DOI:10.1016/j.sna.2018.12.027 期刊:Sensors and Actuators A: Physical 出版年份:2019 更新时间:2025-09-23 15:23:52
摘要: On-chip porous silicon can be fabricated in a number of ways, but perhaps the simplest is a galvanic method that requires no external power supply. While this etch process is relatively simple, the etch is highly dependent on the surface area ratio (SAR) of a backside precious metal and frontside silicon surface, which respectively act as the cathode and the anode of an electrochemical cell. The SAR controls the etch current density, and therefore local variations can create high current densities that have detrimental effects on the quality of the final porous silicon film. The present study investigates the use of patterned backside platinum electrodes with the galvanic etch technique. The use of a patterned backside electrode that mimics the silicon pattern on the frontside, provides a more consistent etch current throughout the entire sample, and thus a more uniform porous silicon film. A triangular shape porous silicon film was tested in this work for comparison to a previous study utilizing an unpatterned electrode. With patterned electrodes, an etch depth variation percentage was observed throughout the length of the film of 8%. This is a considerable improvement over a 108% depth variation observed with a similar frontside silicon pattern and an unpatterned backside electrode.
作者: Nicholas W. Piekiel,Matthew H. Ervin,Christopher J. Morris,Wayne A. Churaman,David M. Lunking,Brian Isaacson
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Investigating the use of patterned backside platinum electrodes to improve the uniformity of galvanic porous silicon fabrication by reducing etch depth variations caused by surface area ratio gradients and edge effects.

The use of patterned backside electrodes significantly improves the uniformity of porous silicon etch depth, reducing variation from 108% to 8% in some cases. Undercutting the electrode by 500 μm further enhances uniformity. This method is beneficial for macroscale patterns and can be improved with better modeling.

The method still shows some edge effects with up to 44% variation, and further optimization through modeling and electrode design is needed to reduce this. The process may require complex backside alignment and is specific to galvanic etching.

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