研究目的
Investigating the use of patterned backside platinum electrodes to improve the uniformity of galvanic porous silicon fabrication by reducing etch depth variations caused by surface area ratio gradients and edge effects.
研究成果
The use of patterned backside electrodes significantly improves the uniformity of porous silicon etch depth, reducing variation from 108% to 8% in some cases. Undercutting the electrode by 500 μm further enhances uniformity. This method is beneficial for macroscale patterns and can be improved with better modeling.
研究不足
The method still shows some edge effects with up to 44% variation, and further optimization through modeling and electrode design is needed to reduce this. The process may require complex backside alignment and is specific to galvanic etching.
1:Experimental Design and Method Selection:
The study uses a galvanic etch method with patterned backside platinum electrodes to improve uniformity. The rationale is to mimic the frontside silicon pattern on the backside to provide a consistent etch current. Theoretical models include electrochemical cell principles and electric field considerations.
2:Sample Selection and Data Sources:
Silicon wafers are 525 μm thick, 1-10 ?·cm, boron doped, with Si3N4 protective layers. Patterns are applied using photolithography. Data sources include SEM and profilometry for depth measurements.
3:List of Experimental Equipment and Materials:
Equipment includes Karl Suss aligner for backside alignment, reactive ion etcher, sputter deposition system for platinum, ion milling system, optical profilometer (Veeco WYKO NT1100), stylus profilometer (Ambios Technology, Inc. XP-2), SEM. Materials include silicon wafers, Si3N4, photoresist (EMB Performance Materials AZ5214), platinum, HF, EtOH, H2O2, NaOH.
4:Experimental Procedures and Operational Workflow:
Steps involve patterning frontside and backside with photoresist and Si3N4 removal, optional MEMS integration, platinum deposition and patterning via ion milling, galvanic etching in HF:EtOH:H2O2 solution for 10-20 minutes, rinsing, drying, and depth measurement after porous silicon removal with NaOH.
5:Data Analysis Methods:
Depth variation is calculated using a formula (depthd - depths)/depths * 100. Profilometry and SEM are used for quantitative analysis.
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