研究目的
To develop a green and facile method for the reduction of graphene oxide to few-layer graphene using Zante currants extract as a natural reducing agent, avoiding the use of hazardous chemicals.
研究成果
Zante currants extract effectively reduces graphene oxide to few-layer graphene, as confirmed by various characterization techniques. This green method is environmentally friendly, cost-effective, and avoids hazardous chemicals, offering a promising approach for large-scale production of reduced graphene.
研究不足
The study does not address the scalability of the synthesis for industrial applications, potential variability in Zante currants composition, and the exact mechanism of reduction by specific compounds in the extract. Optimization of reaction conditions (e.g., time, temperature) may be needed for higher efficiency.
1:Experimental Design and Method Selection:
The study employs a green synthesis approach using Zante currants extract for the reduction of graphene oxide, based on the presence of reducing sugars and polyphenolic compounds. The Hummers method is used for GO synthesis, and characterization techniques include SEM, TEM, Raman, FTIR, XRD, and UV-Vis spectroscopy.
2:Sample Selection and Data Sources:
Graphite powder is used as the starting material for GO synthesis. Zante currants are purchased from the market for extract preparation. All chemicals are analytical grade from Sigma Aldrich.
3:List of Experimental Equipment and Materials:
Equipment includes Perkin Elmer FT-IR Spectrometer, X-ray diffractometer (Rigaku Corporation), Perkin Elmer Lambda 35 UV-Vis spectrophotometer, LabRAM Raman spectrometer, Field Emission Scanning Microscope (SIGMA VP, Zeiss), and HR-TEM (F30 S-Twin, Technai). Materials include graphite, hydrogen peroxide, potassium permanganate, sulphuric acid, nitric acid, ethanol, Zante currants, cellulose membrane, de-ionized water, and ammonia solution.
4:Experimental Procedures and Operational Workflow:
Zante currants extract is prepared by saturating ZC in deionized water at 95°C, followed by filtration. GO is synthesized via the Hummers method involving oxidation of graphite with KMnO4 and H2SO4. Reduction of GO is carried out by adding ZC extract and ammonia to GO suspension, heating at 95°C for 48 hours, followed by washing.
5:Reduction of GO is carried out by adding ZC extract and ammonia to GO suspension, heating at 95°C for 48 hours, followed by washing. Data Analysis Methods:
5. Data Analysis Methods: Characterization data are analyzed using standard techniques: XRD for crystal structure, Raman for defect analysis, FTIR for functional groups, UV-Vis for electronic transitions, SEM and TEM for morphology.
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UV-Vis spectrophotometer
Lambda 35
Perkin Elmer
Recording UV-Vis spectra of GO and FLG
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Raman spectrometer
LabRAM HR800
JY
Determining Raman spectra of GO and FLG
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Field Emission Scanning Microscope
SIGMA VP
Zeiss
Examining morphology of GO and FLG
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FT-IR Spectrometer
Perkin Elmer
Recording IR spectra of GO and FLG on KBr pellets
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X-ray diffractometer
Rigaku Corporation
Investigating crystal structure of GO and FLG
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HR-TEM
F30 S-Twin
Technai
Investigating morphological characteristics of FLG with SAED
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Cellulose membrane
0.45 μm
Filtering Zante currants extract to remove impurities
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