研究目的
To investigate the effects of different molecular chain lengths and side groups on the structure and properties of UV-curable waterborne cathodic electrophoretic deposition coatings.
研究成果
The modified monomers with different chain lengths and side groups significantly influence the properties of UV-curable CED coatings. Soft chains improve flexibility but reduce hardness, while rigid groups enhance thermal stability and mechanical properties but lower photopolymerization rates and cause phase separation. The coatings exhibit good adhesion, flexibility, and corrosion resistance, making them suitable for industrial applications with further optimization.
研究不足
The study focused on specific modified monomers and may not generalize to all types; the photopolymerization rate was lower with rigid groups, indicating potential inefficiencies; phase separation occurred with rigid groups, affecting film smoothness.
1:Experimental Design and Method Selection:
The study involved synthesizing modified monomers with different chain lengths and side groups, incorporating them into acrylic copolymers, and preparing UV-curable CED coatings. Methods included radical polymerization, photopolymerization, and electrophoretic deposition.
2:Sample Selection and Data Sources:
Samples were synthesized in the laboratory using specific chemicals purchased from suppliers. Data were obtained from characterization techniques like FT-IR, NMR, GPC, DSC, TGA, SEM, and performance tests.
3:List of Experimental Equipment and Materials:
Materials included dimethylaminoethyl methacrylate, 2-hydroxyethyl acrylate, butyl acrylate, methyl methacrylate, styrene, azodiisobutyronitrile, isophorone diisocyanate, benzaldehyde, 2-naphthaldehyde, methyl acrylate, 2-ethylhexyl acrylate, lactic acid, ethylene glycol monobutylether, di-n-butyltindilaurate, triethylene diamine, 2,6-di-tert-butyl-p-cresol, 2-hydroxy-2-methyl-1-phenyl-1-propanone (Darocur 1173), and deionized water. Equipment included FT-IR spectrometer (Bruker VERTEX 70), NMR spectrometer (Bruker AVANCE III HD 400), UV-Vis spectrophotometer (UV-3000), photo-DSC (CDR-1), GPC (GPCmax VE 2001 Malvern), DSC (DSC 200F3 Netzsch), particle size analyzer, contact angle analyzer (Pocket Goniometer PGX+), TGA (NETZSCH TG209), SEM (HITACHI SU-8220), thickness gauge (QNIX 4200), pencil hardness tester, adhesion tester (QFH-HG600), impact hammer, flexibility tester (QTX), and salt spray test chamber.
4:Experimental Procedures and Operational Workflow:
Synthesis of modified monomers, acrylic copolymers, and CED coatings; characterization using spectroscopic, thermal, and mechanical methods; performance testing including hardness, adhesion, flexibility, impact resistance, and corrosion resistance.
5:Data Analysis Methods:
Data were analyzed using software for DSC and TGA, and statistical methods for contact angle and performance tests.
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FT-IR Spectrometer
VERTEX 70
Bruker
Performing Fourier-transform infrared spectra for characterization of materials.
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NMR Spectrometer
AVANCE III HD 400
Bruker
Recording 1H-NMR spectra for structural analysis.
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GPC System
GPCmax VE 2001
Malvern
Examining molecular weights and polydispersity of resins.
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SEM
SU-8220
HITACHI
Conducting scanning electron microscopy for surface morphology analysis.
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Photoinitiator
Darocur 1173
Aldrich
Used as a free radical photoinitiator for UV curing.
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UV-Vis Spectrophotometer
UV-3000
Testing optical properties of samples.
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Photo-DSC Instrument
CDR-1
Conducting UV photo-DSC experiments for curing kinetics.
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DSC Instrument
DSC 200F3
Netzsch
Performing differential scanning calorimetry for thermal analysis.
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Contact Angle Analyzer
Pocket Goniometer PGX+
Measuring static contact angles for surface energy determination.
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TGA Instrument
TG209
NETZSCH
Determining thermal stability by thermogravimetric analysis.
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Thickness Gauge
QNIX 4200
QuaNix
Measuring coating thickness.
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