1：Experimental Design and Method Selection:

The study utilized a capillary bridge dewetting method to fabricate aligned DLC microstripe arrays doped with molecular motors. The method was chosen for its ability to precisely control the formation and dewetting process, resulting in highly ordered microstructures. Theoretical models involved the influence of molecular motion on electron orbital overlap and carrier transport.

2：Sample Selection and Data Sources:

Samples were prepared using triphenylene derivative HAT8 as the DLC and chiral overcrowded alkene M1 as the molecular motor. Different weight ratios of M1 (2.5 to 15 wt%) were doped into HAT8, dissolved in chlorobenzene at a concentration of ≈20 mg mL?

3：5 to 15 wt%) were doped into HAT8, dissolved in chlorobenzene at a concentration of ≈20 mg mL?List of Experimental Equipment and Materials:

1. 3. List of Experimental Equipment and Materials: Equipment included a silicon wafer with structured pillars, flat silicon substrates with SiO2 layer, oxygen plasma instrument (DT-03), UV–vis–NIR spectrophotometer (Lambda 950, Perkin Elmer), field-emission scanning electron microscopy (Hitachi S-4800), polarized optical microscope (Carl Zeiss Axio Vision SE64) with CCD camera and Linkam hot stage, 2D wide-angle X-ray diffractometer (Bruker Discover), Keithley 4200 SCS semiconductor parameter analyzer, and Suss PM5 analytical probe station. Materials included HAT8, M1, chlorobenzene, and FAS-modified silicon templates.

4：Experimental Procedures and Operational Workflow:

The solution was sandwiched between a structured silicon wafer and a flat substrate, heated to 60°C for solvent evaporation, leading to dewetting and formation of microstripes. Electrical properties were measured under UV irradiation (365 nm LED lamp at various intensities) using gold electrodes stamped on the samples. Thermal treatment involved heating to 72°C and cooling at 0.1°C min?1 for recovery.

5：1°C min?1 for recovery. Data Analysis Methods:

5. Data Analysis Methods: Data were analyzed using J–V curves, cyclic voltammetry, constant current charge-up curves, and POM/SEM/XRD for morphological and alignment characterization. Statistical analysis included repeatability tests and correlation between UV intensity, doping concentration, and current density.