研究目的
To decompose ethylene gas and remove by-products like ozone and carbon monoxide using a packed-bed dielectric barrier discharge plasma reactor with Ag nanoparticle-loaded zeolite catalyst to maintain fruit freshness during transport.
研究成果
The Ag nanoparticle-loaded zeolite in PBDBD effectively removed ethylene to below 1 ppm and significantly reduced ozone and carbon monoxide by-products, demonstrating high potential for fruit freshness preservation in transport containers with minimal harmful emissions.
研究不足
The study may have limitations in scalability to real-world transport conditions, potential catalyst degradation over time, and the need for further validation of intermediate product identification and decomposition pathways.
1:Experimental Design and Method Selection:
A packed-bed dielectric barrier discharge (PBDBD) plasma reactor was used to decompose ethylene gas. The method involved generating plasma with a pulse switching power supply and using Ag nanoparticle-loaded zeolite as a catalyst to enhance removal efficiency and reduce by-products.
2:Sample Selection and Data Sources:
Simulated gas mixture of ethylene (200 ppm), oxygen (10%), carbon dioxide (10%), and nitrogen (balance) was used to mimic transport container conditions. Gas samples were analyzed post-treatment.
3:List of Experimental Equipment and Materials:
Reactor with glass tube, aluminum tape electrode, stainless steel rod, pellets (glass, zeolite, Ag-zeolite), pulse power supply, mass flow controllers, digital oscilloscope, high-voltage probe, voltage probe, ozone monitor, gas detector tubes, FT-IR spectrophotometer.
4:Experimental Procedures and Operational Workflow:
Gas was flowed at 5 L/min into the reactor, plasma was generated by applying voltage, and concentrations of ethylene, ozone, and CO were measured. V-Q Lissajous figures were used to calculate energy input.
5:Data Analysis Methods:
Concentrations were measured using detectors and FT-IR; energy density was calculated from V-Q diagrams; statistical analysis of removal efficiencies was performed.
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Digital Oscilloscope
DS-5324
Iwatsu
Measure voltage waveforms during the experiment.
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High Voltage Probe
P6015A
Tektronix
Measure high voltage applied to the electrode.
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Voltage Probe
SS-0130R
Iwatsu
Measure voltage across the charge measurement capacitor.
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FT-IR Spectrophotometer
FT/IR-4200
JASCO
Analyze components in the exhaust gas and measure carbon monoxide concentration.
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Mass Flow Controller
CMQ series
Yamatake
Regulate gas flow rates in the experimental setup.
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Pulse Power Supply
Sawafuji Electric
Generate plasma in the reactor by applying pulsed voltage.
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Ozone Monitor
EG-2001
Ebara Jitsugyo
Measure ozone concentration in the exhaust gas.
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Gas Detector
GV-100S
GASTEC
Sample and detect gas concentrations, specifically ethylene.
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Gas Detection Tube
172, 172L
GASTEC
Detect specific gas concentrations, used for ethylene measurement.
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